475不锈钢显微结构分析.docVIP

475不銹鋼顯微結構分析 The Studies of the Microstructures of the Costom 475 Stainless Steel 研究生：余承軒 Cheng-Hsuan Yu 指導教授：趙志燁 Chih-Yeh Chao 【摘要】 合金經970℃和1050℃固溶1小時後，其顯微結構為板狀α及殘留沃斯田鐵，溫度越高殘留沃斯田鐵含量越多，此板狀α 或稱麻田散鐵，c/a≒1 結構為體心立方結構 B.C.C. ，其晶格常數為a 0.289nm，而殘留沃斯田鐵結構為面心立方結構 F.C.C. ，晶格常數a 0.360nm。於-80℃/8H深冷處理後，將固溶時之殘留沃斯田鐵完全轉變為板狀α結構，此時之晶格常數為a 0.289nm。 經時效 450℃、550℃及650℃ 處理，在450℃時可發現α相及沃斯田鐵相之產生，其α相之晶格常數為a 0.289nm。而在550℃和650℃時可發現L12 Ni3Al 結構之析出物於基地內整合析出，此時之結構為板狀α與沃斯田鐵，並且有L12 面心立方結構 之析出物，其晶格常數為a 0.375nm。並且可以觀察出時效溫度550℃提高至650℃時，其Ni3Al之析出物由微粒狀轉變為顆粒狀，沃斯田鐵含量大量增加。與其他學者比較，固溶溫度提高至980-1050℃後，其B2相 NiAl 之析出物並未被發現。 關鍵字：顯微結構、板狀α、沃斯田鐵、晶格常數 【Abstract】 Being solution heat treatment SHT on 970℃/1H or 1050/1H, and quenching room-temperature the microstructure of the alloy is the α phase and retained austenite. The higher SHT temperature would posses the higher retained austenite. This plate-α called matensite belong to the body-centered cubic B.C.C. structure with the lattice parameter a 0.289nm. The retained austenite belongs the face-centered cubic F.C.C. structure with lattice parameter a 0.360nm. After -80℃/8H subzero heat treatment. The retained austenite would transform into plate-α. During the 450℃ aging processes, the α-plate martensite would be decompose to α + austenite phase, increasing the aging temperature to 550-650℃.The L12-phase Ni3Al particles would be found within the matrix . The lattice parameter of the L12-phase is a 0.375nm. Compared with the other workers studies , increasing the SHT temperature to 980-1050℃, the precipitation of the B2-phase NiAl will be inhibited. Keywords：Microstructure, α phase, Austenite, Subzero treatment