应用量子点改善染料敏化太阳能电池效率之研究.doc

應用量子點改善染料敏化太陽能電池效率之研究 Applications of the Quantum Dot in Improving the Efficiency of Dye-Sensitized Solar Cells 研究生：周峰丞 Chou, Feng-Cheng 指導教授：周春禧 Chou, Chuen-Shii 【摘要】 本研究採用水解法，製備具有量子點硫化鉛 Quantum Dot PbS 硫化鉛、染料敏化太陽能電池、二氧化鈦、水解法、FTO導電玻璃Molar concentration composite particles of TiO2 P-25 and PbS through hydrolysis. Coating the colloid on the FTO immersed 0.05M TiCl4 aqueous solution substrate forms a thin film of titanium dioxide then sintered by High Temperature Furnace. The next step is to coat the colloid on the control group immersed 0.05M TiCl4 aqueous solution substrate to form the TiO2/PbS thin film and then sintered by High Temperature Furnace. The area is 0.25 cm2.The working electrode with a TiO2/PbS thin film was coated with the N-719 Ruthenium by immersing the plates in a warm 70℃ solution of this dye for 6 hours. In addition, a thin film of platinum was deposited on the FTO-glass substrate of the counter electrode. Finally, the Dye-Sensitized Solar Cell DSSC was assembled, and the short-circuit photo-current, the open-circuit photo-voltage and the power conversion efficiency of DSSC were measured using a XES-310S 300W I-V measurement system. This study proved that using the method of hydrolysis to make TiO2/PbS and composite particles is able to avoid Quantum Dot, PbS, and direct contact of electrolyte solution direct contact that produce reactions causing rust. It can boost the absorbance, wavelength, and power conversion efficiency of dye-sensitized solar cell DSSC . This experiment power conversion efficiency of W6-TiO2 P-25 is 5.11% and the efficiency of the dye-sensitized solar cell DSSC of composite particles is 6.05%. Keywords：PbS, dye-sensitized solar cells DSSC , TiO2, hydrolysis method, FTO