稀土掺杂的硅酸荧光粉.doc

毕 业 论 文 稀土掺杂的硅酸盐荧光粉的制备及发光性能研究 专 业 材料科学与工程 学生姓名 班 级 B材料 学 号 指导教师 完成日期 201年0 月 发光材料发射光谱丰富光谱的位置及强度关键词:Research on the preparation and luminous performance of rare earth doped silicate phosphor Abstract:In numerous luminescence materials, silicate substrate luminescent material has the emission spectrum is very rich, the location and intensity of spectrum controllable and material advantages of long afterglow time, attracting widespread attention and research.At present, the silicate based fluorescent powder as a kind of stable luminescent material preparation of substrate, are widely used in lighting, energy, screen display, etc. In this paper, by adopting the method of high temperature solid instead should be synthesized Tb3 +, Ce3 + single admixture Tb3 +, Ce3 + codoping CaAl2Si2O8 phosphor and Tb3+, Ce3+, Pr3+ single admixture Tb3+, Ce3+ codoping Mg2SiO4 phosphors, and their fluorescence properties are studied.Paper main results are as follows:Through the research of the preparation of doped with different concentrations of Tb3+ ion CaAl2Si2O8 phosphors, the results show that at 1140℃ temperature preparation CaAl2Si2O8: Tb3+ phosphor in Tb3+ doping concentration for 3 mol % has the best emission intensity;We were prepared under different temperature Mg2SiO4:Ce3+ phosphor, their fluorescent properties was studied, the results show that in 1380 ℃ calcination 1 mol% doping concentration of Mg2SiO4: Ce3+ phosphor can achieve best emission intensity;Studied the different concentrations of Pr3+ phosphors doped Mg2SiO4, the results show that although the doping concentration increased, the emission intensity of phosphor decline after rising first, but at 650 nm to 700 nm, show red light emitting characteristics;In Tb3+, Ce3+ co-doping CaAl2Si2O8 and Mg2SiO4 phosphors, the former was not observed Ce3+-Tb3+energy transfer phenomenon, for the latter, using 340 - nm inspire Mg2SiO4: Ce