晶体学衍射技术.ppt

Bragg diffraction Bragg diffraction Constructing Brillouin Zones Is the compound known?Crystallographic Structure Databases La2(Co,Ti）17化合物 Nonmagnetic semiconductors ?DMS Diluted magnetic semiconductors Interesting problems Mn-doped ZnO Mn-doped ZnO Mn-doped ZnO Gd5(Si1-xGex)4成分、温度、晶体结构和磁性的关系 Lattice parameters, cell volume and Ln-O distances of Ln3GaO6 Lattice parameters and cell volume of Tb and Tm doped Y3GaO6 Saturation range of the PL intensity for the Tb3+, Tm3+ doped Y3GaO6 确定新相（新化合物，新材料） ICSD (Minerals and Inorganics) http://www.fiz-karlsruhe.de/ Minerals and Inorganic Over 60000 entries Cambridge Structure Data Bank） http://www.ccdc.cam.ac.uk Organics Organometallics Over 250000 entries ICDD diffraction data http:/ Inorganic Organic Over 140000 entries NIST Crystal Data /srd/nist3.htm Inorganic Organic Over 230000 entries a= 8.5092(1)?, c= 12.3575(1)? , V=774.9(1)?3 0.0961 0.0 0.0 *Co+Ta 6c 绿 0.1548 0.0 0.5 Co 18h 紫 0.0 0.0 0.2860 Co 18f 兰 0.5 0.0 0.5 Co 9d 黄 0.3470 0.0 0.0 La 6c 绿 z y x Atom site Q.L. Liu et al., Appl. Phys. Lett. 71 (1997)1869 Q.L. Liu et al., Appl. Phys. Lett. 71 (1997)1869 测定固溶体的类型和固溶度 测定相图的固溶线 Q.L. Liu et al, J.Phys.: Condens. matter 11 (1999)9797 Q.L. Liu et al, J. Alloys and Compounds 297 (2000)33 Q.L. Liu et al, J.Phys.: Condens. matter 10 (1998)179 Ti1-xSnxO2体系化合物晶胞体积随成分的变化 B.J. Sun, Q.L. Liu et al., J. Alloys Compounds, jalcom15480 (2007) A: Ferromagnetic semiconductors EuO, EuS, EuSe, CdCr2S4 (late1960s-early1970s) B: 稀磁半导体 DMS C: Nonmagnetic semiconducors H. Ohno, Science 281(1998)951 II-VI semiconductors CdTe ZnS 1980s III-V semiconductors GaAs GaN AlN 1990s Oxide semiconductors ZnO TiO2 SnO2 recently T. Dietl et al, Science 287(2000)1019 要求室温铁磁性和半导体性 成分 dopants content direct Mn-Mn interaction: antiferromagnetic dilute: Mn-carriers-Mn: ferromagnetic carriers: holes /electronic concent