现代分析原理-二章.pptVIP

* .Determine the composition of the compound and acid-base dissociation constant The determination of the composition of the compound 1.Mole ratio method We can determine the composition of the compound (complex ratio) and stability constant Suppose the complex reaction is :M + nR＝MRn Usually we fix the concentration of the metallic ion M , increase the concentration of the complexing agent gradually . ligand is R, obviously, R should be colorless or not remarkably absorbs in the designation wavelength range. Then dilute to the identical volume, obtains a serie