有機小分子凝胶的制备.docVIP

本科生毕业论文（设计） 酰胺类有机小分子凝胶的合成 二级学院 ： 化学科学与技术学院 专 业 ： 化本一班 年 级 ： 2010级 学 号 ： 2010364132 作者姓名 ： 谢家敏 指导教师 ： 苗碗根教授 完成日期 ： 2014年5月10日 酰胺类有机小分子凝胶剂的合成 专业名称：化本一班 申 请 人：谢家敏 指导教师：苗碗根 论文答辩小组 组 长： 苗碗根 成 员： 谢家敏 邹军境 苏海连 论文成绩： 目录 1 前言 5 1.1小分子凝胶的概述 5 1.1.1小分子凝胶的分类 5 1.1.2 小分子凝胶的制备 6 1.2小分子凝胶的应用 6 1.3 酰胺类有机小分子凝胶 7 1.4本课题研究的目的及内容 7 2 酰胺类有机小分子凝胶剂的制备 8 2.1 实验试剂与实验仪器： 8 2.1.1 实验试剂： 8 2.1.2 实验仪器 8 2.2 4,4，-联苯二甲酰胺类凝胶剂的合成 8 2.2.1 实验原理 8 2.2.2 4,4，-联苯二甲酰氯的制备 9 2.2.3己二胺联苯二甲酸的制备 9 3结果与分析 9 3.1 4,4，-联苯二甲酰氯的红外谱图分析 9 3.2 4,4，-联苯二甲酰胺-己二胺的红外谱图分析 11 3.3 结论 11 The Synthesis of Organic Low Molecular Gels Based on Amide Author: Xie Jiamin Instructor: Professor Miao Wangen （Chemistry Science and Technology School, Zhanjiang Normal University, Zhanjiang, 524048 China） Abstract: In recent years, the small molecule gel due to its unique application value to become an important research field of super-molecular chemistry. The molecular gel and its self-assembly fiber network is more and more attention, but people no longer satisfied with finding the new gel factor. How to define accurately the gel factor，s self-organizing manner, endow it more functional and develop its potential application value in the gel .It，s has become the main current research hot point. In this paper, it used 4,4-Biphenyldicarboxylic acid and 1,6-Diaminohexane as the raw material to design a simple synthetic to product a small molecular gels of double amides. At first，under anhydrous conditions, taking the reaction of 4,4-Biphenyldicarboxylic acid and Thionyl chloride (SOCl2) it can generate the middle of products —4,4-Biphenyldicarboxylic chloride. Then the chloride atom was replaced by the 1,6-Diaminohexane which is amino dehydrogenation .Thus it prepared the objective product. The last，testing the product by Infrared spectrum and drawing the conclusion: it has been synthesiz