空氣氧化再生Pd-C催化剂的研究9-3.docVIP

空气氧化法再生Pd/C催化剂的初步研究 Preliminary study of Air oxidation regenerated Pd/C catalyst 摘要：研究了空气氧化法再生PTA精制用Pd/C催化剂的过程，以4-CBA为评价指标，考察了氧气含量、氧化温度、氧化时间和空气流量对Pd/C催化剂活性的影响，用XRD和TEM对再生Pd/C催化剂进行表征。结果表明： 空气氧化再生Pd/C催化剂的适宜条件为空气流量80mL/min， 氧化时间60min， 氧化温度180℃，4-CBA的转化率可达到99.34%；TEM表征结果表明空气氧化再生能够使催化剂中大颗粒的金属钯明显减小，可以使得Pd晶粒在载体表面有效地再分散。 Abstract: In this study the process of air oxidizing regeneration of Pd/C catalyst used in PTA refining is researched. Based on the indication of 4-CBA, factors including the oxygen content, oxidation temperature, oxidation time and air flow were evaluated on how they impacted the ac