WC_Co梯度硬质合金的制备及渗碳对其组织的影响_肖逸锋.docxVIP

DOI :10.13289/j.issn.1009 -6264.2008.01.019第29卷 第1期材 料 热 处 理 学 报Vol .2 9 No .12 0 0 8 年 2月TRANSACTIONS OF MATERIALS AND HEAT TREATMENTFebruary2 00 8WC-Co 梯度硬质合金的制备及渗碳对其组织的影响肖逸锋1 , 2 , 贺跃辉1 , 丰 平1 , 谢 宏1, 3 , 马自省1 ,3 , 张丽娟1 , 黄自谦1 , 黄伯云1(1 .中南大学粉末冶金国家重点实验室, 湖南长沙 410083 ;2 .湘潭大学机械工程学院 , 湖南湘潭 411105 ;3 .株洲硬质合金集团有限公司, 湖南株洲 412000)摘 要:采用光学金相检测、扫描电镜分析、能谱分析等方法对 WC-6Co 硬质合金渗碳处理后的成分和梯度 组织结构进行分析。 结果表明:对硬质合金渗碳处理后可形成显微组织和钨、钴含量的梯度分布, 其特征是 合金表层和次表层的η相已经完全消失 , 属正常的 WC +γ两相组织, 合金的芯部依然是含η相的三相组织, 中间形成了一个富钴层;碳原子的扩散和液相钴的流动是形成梯度的原因;在各渗碳温度下, 合金的梯度结 构厚度均随渗碳时间的增加而增加;在渗碳时间和渗碳温度相同的情况下, 合金的梯度层厚度均随合金初 始总碳含量的增加而增厚。 渗碳处理后外表面的 WC 晶粒可能会产生一定的粗化现象。关键词:硬质合金; 渗碳处理; 梯度组织中图分类号:TG135.5 ; TG156.81 文献标识码:A 文章编号:1009-6264(2008)01-0116-05Preparation of WC-Co gradient cemented carbides and effects of carburizing on its microstructureXIAO Yi-feng1, 2 , HE Yue-hui1 , FENG Ping1 , XIE Hong1, 3 , MA Zi-xing1 ,3 ,ZHANG Li-juan1 , HUANG Zi-qian1 , HUANG Bai-yun1(1 .State Key Laboratory of Powder Metallurgy , Central South University , Changsha 410083 , China ; 2 .School of Mechanical Engineering , Xiangtan University , Xiangtan 411105 , China ;3 .Zhuzhou Cemented Carbides Group Co Ltd , Zhuzhou 412000 , China)Abstract :A WC-Co gradient cemented carbides was prepared by microstructure of the alloy was investigated by optical microscopy ,carburizing WC-Co cemented carbides with different carbon content.The SEM and EDS analysis.The results show that microstructure with gradienttungsten content and cobalt content is obtained by carburizing the WC-Co cemented carbides with lower carbon content.The microstructure of the carburized layer with gradient characteristics consists of the surface layer without ηphase and the cobalt-rich sub-surface layer with normal WC + γphases, and tungsten content slightly decreases but cobalt obviously increases from surface layer to core , a cobalt-rich layer forms in the middle layer , whereas ηphase still exists in the core .The formation of gradient microstructure is possibly at