第五章煤的间接液化.pptVIP

* * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * 甲醛生产条件 反应温度控制在600~700 度 最佳氧醇比 适宜水蒸气量 适宜的接触时间 工艺流程 作业 简述甲醇、二甲醚的生产原理和主要工艺过程。 试述Monsanto低压法羰基合成制醋酸的原理和主要工艺过程。 * * * * * * * * * * * * 强氧化剂： 氯酸铵、高锰酸钾等 过氧化物：过氧化苯甲酰、过氧化甲乙酮等问问 * * Before you handle a chemical for the first time, OSHA recommends that you read the Material Safety Data Sheet. An MSDS is written as a orse-case?scenario to cover all possible uses and applications. It is also written for s-is?product, not the dilute form you are exposed to in the system. I want to spend just a few minutes going over this important document and how to interpret the information. （Chemical Abstracts Service, CAS）化学文摘服务社 Section 3 gives you a quick emergency overview of the product, and important health effects that might occur with over-exposure to a chemical. Primary route of exposure is the most likely method you would be exposed to the chemical. Notice on this example that this product has an acute eye effect of orrosive to eyes? It is also a skin sensitizer, this is an allergic reaction to a chemical that affects maybe 1 out of thousands of people. Each time the person is exposed to the chemical it takes less exposure to cause a reaction. Another source of product information that is usually overlooked is the label. It is right there on the container you walk by and work with everyday. All labels will provide you with caution statements, first aid, ERG numbers and HMIS codes. In addition, biocide labels will provide active ingredients, directions for use, and an EPA registration number. 气化反应器类型 固定床反应器 反应温度低 使用沉淀铁催化剂，不存在分离问题 积碳现象少 反应器尺寸小 操作方便 催化剂床层压降大 催化剂更换困难 气化反应器类型 流化床反应器 熔铁粉末催化剂 强化了传热、传质 生产能力高 操作温度较高 重质氢的选择性差 结构复杂 操作费用高 设备磨损大 气化反应器类型 桨态床反应器 三相反应器 气化炉出来的合成气能直接使用 传热好 反应温度低 传质阻力大 液固分离 南非Sasol间接液化工艺 南非Sasol间接液化工艺 南非Sasol间接液化工艺 南非Sasol间接液化工艺 其他合成液体燃料工艺 荷兰SMDS工艺 碳一化工主要产品 煤制碳一化工主要产品 碳一化工 含一个碳原子的物质为原料，合成化工产品和液体燃料的生产过程 合成气制燃料，甲醇，低碳醇，醋酸，低碳烯烃，燃料添加剂等 碳一化合物 CO,CO2,CH4,CH3OH 甲醇合成 木醇 甲醇最早从木材干馏中得到 化工原料 燃料 良好的燃料性能