1107020224钱茜茜预案.doc

缩氨基硫脲三苯胺甲醛Cu（Ⅱ）配合物 制备、表征及光学性能的研究 学生：钱茜茜（指导老师：陈士昆） （淮南师范学院化工与材料工程学院） 摘要：本文以无水乙醇为溶剂，在高温回流的条件下将三苯胺甲醛与氨基硫脲反应，制备缩氨基硫脲三苯胺甲醛配体L,配体L与铜离子反应制备成新型的席夫碱Cu2+配合物。通过红外光谱对其进行表征，分析合成配体过程中的-C=O与-NH2消失，可知这两个基团发生了反应，在配合物形成的过程中，配体的硫酮式结构变成了硫醇式的结构。通过分析紫外光谱可知，在该配合物中有大的共轭体系。 关键词：三苯胺甲醛；氨基硫脲；紫外光谱；红外光谱 Preparation , Characterization and Study of properties of thiosemicarbazone triphenylamine and Cu2+ complex characterization Student:qianxixi (Faculty Adviser :Chen Shikun) (Department of chemical and materials engineering,Huainan Normal University) Abstract: Because of the Schiff base molecules containing thiosemicarbazide class can coordination atoms N and S, So thiosemicarbazide kind of Schiff base compounds by S and N atoms with unpaired electron to chelate with metal ions, Schiff base complexes formed thiosemicarbazide class. Because of the Schiff base on synthetic flexibility, ligand with metal ions, easily, this kind of structure of complexes is diversiform, special nature, in the field of chemistry, biology and materials science have broad application prospects. Taking anhydrous ethanol as solvent, under the condition of high temperature reflow three aniline formaldehyde and thiosemicarbazide reaction, preparation of shrinkage thiosemicarbazide three aniline formaldehyde ligand L, ligand L preparation into new schiff base reaction with copper ions Cu2+complexes. Were characterized by its infrared spectrum, the analysis in the process of synthesis of ligands -C=O and disappear -NH2, illustrates the two groups in the reaction, in the process of the complexes formed by ligand into mercaptan sulfur ketone type structure type of structure. By ultraviolet spectrum, whether in the complexes have big conjugate system, Key words: Aminothiourea； triphenylamine formaldehyde; UV spectrum； Infrared spectrum 前言 近年来，Schiff碱及其金属配合物在抗菌药物、荧光药物、消毒药物等方面的研究很多[1]。具有多样的结构，特殊的性质，在化学、生物学及材料学科等科学领域具有广泛的应用前景[2]。且作为新型跟踪试剂、催化剂等方面也有着很广泛的应用，尤其表现在有机催化反应，电催化等等方面，该类配合物发挥着越来越重要的作用[3-4]。Schiff碱与金属离子反应，结合现代仪器对其进行色谱