化学反应工程Chapter 4 A Special Problem of An Exothermic.pptVIP

Chapter 4 A Special Problem of An Exothermic Reactor Heat Stability Outline Introduction Heat Stability Analysis for Mixed Flow Reactor in Steady State Heat Stability Analysis for Mixed Flow Reactor in Non-steady State Heat Stability Analysis for Other Reactors Example Introduction to Heat Stability of An Exothermic Reactor Heat Stability Analysis for Mixed Flow Reactor in a Steady State Heat Stability Analysis for Mixed Flow Reactors in Non-steady State * * Heat stability of a reactor is a particular behavior from an exothermic reaction system which comes from nonlinearity of the reaction rate in relation to temperature。We will analyze the heat stability by using the first order kinetics as an example. Mass balance for Mixed Flow Reactor, and Heat Balance, 令 We have In the Figure, Qg~T curve stands for heat release rate in a reaction；Qr~T cure stands for the heat exchange rate with surroundings. To keep a reaction in a steady state has to remove all heat released from a reaction. There are two ways to remove heat from the reaction system. One way is to increase temperature of reaction mixture which probably remove reaction in a part or all heat of reaction; another way is to exchange heat with surrounding media through a heat exchange area. Thus, to keep a reaction system operated in a steady state, the heat balance condition is to be satisfied as below and necessary heat stability condition (Slope condition in relation to the heat release rate curve and heat exchange rate curve) which reflects enough capability of self balance responsible for a tiny disturbency. or Here so called capability of self balance is a capability to behave in self meditation in a system, for example, a disturbency of temperature at point C lets QrQ g, temperature is going to be reduced from that point, but once the disturbency disappears, temperature of the system is about to go back to point C again. On the other hand, a negative temperature disturbency will let QgQr，further lift