裂解气相色谱-质谱联用法鉴别聚乳酸纤维和聚酯纤维.docVIP

裂解气相色谱-质谱联用法鉴别聚乳酸纤维和聚酯纤维 【摘要】采用热裂解气相色谱-质谱联用技术（Py/GC-MS）建立了聚乳酸（PLA）纤维和3种聚酯纤维（聚对苯二甲酸乙二酯（PET）纤维、聚对苯二甲酸丙二酯（PTT）纤维、聚对苯二甲酸丁二酯（PBT）纤维）的鉴别方法。裂解温度为700 ℃时，可以最大限度同时显示聚乳酸纤维和聚酯纤维样品特征。PLA纤维、PET纤维、PTT纤维和PBT纤维分别鉴别出8种、14种、16种和13种主要裂解产物。PLA纤维的特征性裂解产物是：D,L-丙交酯、内消旋丙交酯；PET纤维的特征性裂解产物是：苯甲酸乙烯酯、苯二甲酸双乙烯酯、二苯甲酸-1,2-乙二醇酯、苯甲酸乙酯；PTT纤维的特征性裂解产物是：苯甲酸丙烯酯、间苯二甲酸二烯丙酯、1,4-苯二甲酸-二-2-丙烯基酯、二苯甲酸-1,3-丙二醇酯；PBT纤维的特征性裂解产物是：苯甲酸丁烯酯、1,4-苯二甲酸-双-3-丁烯酯。【关键词】；Identification of poly(lactic acid) fiber and polyester fibers by pyrolysis gas chromatography - mass spectrometry ABSTRACT: A identification method of poly(lactic acid) fiber and three polyester fibers was established by pyrolysis gas chromatography - mass spectrometry (Py/GC-MS). The polyester fibers included polyethylene terephtalate (PET) fiber, polytrimethylene terephthalate (PTT) fiber and polybutylene terephthalate (PBT) fiber. As shown by the experimental results, it was better to choose 700 ℃ as the pyrolytic temperature in the identification, as more significant characteristic informations were displayed simultaneously. PLA fiber, PET fiber, PTT fiber and PBT fiber were identified 8 species, 14 species, 16 species and 13 species of main pyrolysis products. PLA fiber’s characteristic pyrolysis products were meso-lactide and D,L-lactide. PET fiber’s characteristic pyrolysis products were vinyl benzoate, diethylene terephthalate, dibenzoate-1,2-ethanediol and ethyl benzoate. PTT fiber’s characteristic pyrolysis products were propenyl benzoate, diallyl isophthalate, diallyl terephthalate and 1,3-propanediol dibenzoate. PBT fiber’s characteristic pyrolysis products were butenyl benzoate and bis-3-butenyl-1,4-terephthalate. Key word: Poly(lactic acid) fiber; Polyester fibers; Identification; Pyrolysis gas chromatography - mass spectrometry 聚酯纤维是使用最广泛的合成纤维，由有机二元酸和二元醇缩聚而成的聚酯经纺丝所得的合成纤维。目前聚酯纤维主要有：聚对苯二甲酸乙二酯（PET）纤维、聚对苯二甲酸丙二酯（PTT）纤维、聚对苯二甲酸丁二酯（PBT）纤维。?聚乳酸纤维是采用可再生的玉米、木薯等淀粉原料，经发酵制取乳酸，然后由乳酸聚合成树脂，最后通过纺丝而制成，所以聚乳酸纤维又称为玉米纤维。是一种可完全生物降解的合成纤维具有优良的生物兼容性和可降解性，具有与聚酯纤维相似的物理机械性能