有机质谱简介课件.pptVIP

离子源 电子轰击源（Electro-Impact source） EI 液相色谱－质谱联机的接口 电喷雾电离（Electro Spary Ionization, ESI） TurboIonSpray Source: TurboIonSpray - Ion Evaporation Element Mass Average mass of all natural isotopes Carbon Abundance Integer Mass 12C = 12.0000 Da 98.91% 12 13C = 13.0034 1.09% 13 12.0000×0.9891 + 13.0034×0.011 = 12.011 Common adducts POSITIVE MODE M+Na, 22 Da. higher than M+H M+K, 38 Da. higher than M+H M+Li, 9 Da. higher than M+H M+NH4, 18 Da. higher than M+H NEGATIVE MODE TFA, 114 Da. higher then M-H Acetate, 60 Da. higher then M-H Formate, 46 Da. higher then M