聚醋酸乙烯酯白乳胶的合成工艺-毕业论文.docVIP

目 录 前 言 1 1. 实验方法 2 1.1仪器与试剂 2 1.1.1 仪器 2 1.1.2 试剂 2 1.2 实验基本配方 2 1.3 均聚乳液的制备工艺及操作方法 2 1.4 聚醋酸乙烯酯乳液的共聚改性研究 3 1.5性能测试 3 1.5.1 固含量测试 3 1.5.2粘度测试 3 1.5.3 聚合稳定性 3 1.5.4稳定性 3 1.5.5强度测试 4 1.5.6耐水性测试 4 2. 反应条件对聚合反应的影响 4 2.1乳化剂对乳液聚合的影响 4 2.2引发剂用量对乳液性能的影响 5 2.3温度对聚合过程的影响 6 2.4 反应时间的影响 6 3.聚醋酸乙烯酯乳液的性能研究 7 4. 结 论 9 参考文献 10 摘 要 聚醋酸乙烯酯又称为白乳胶，在日常生活中应用广泛，但由于自身的固有缺点，使其应用受到限制。水溶性聚醋酸乙烯酯由醋酸乙烯酸酯类单体共聚而成的，具有无毒无味，不燃不爆，无污染，可以根据不同用途生产具有不同使用性能的白乳胶等优点。本文研制出一种粘接强度高、耐水性良好的环保水性胶粘剂，论述了以醋酸乙烯酯为单体、过硫酸铵为引发剂、合成环保型水溶性白乳胶的过程。通过实验表明，制造粘结性能好水溶性好的白乳胶受实验中的引发剂的用量、反应温度、反应时间、酸碱度及单体配比影响，且得出一个较好的制备条件：温度70±2℃；引发剂4.7%；最佳时间50~70min。此时产品基本符合应用的要求，产品的颜色成白色，粘稠液体。 关键词：聚醋酸乙烯酯；乳液聚合；环保 Abstract Polyvinyl acetate latex, also known as white, in their daily life widespread use, but because of its own inherent weaknesses, its application is restricted. Water-soluble polyvinyl acetate from vinyl ester monomers from the copolymer is non-toxic and tasteless, non-combustion, pollution-free, According to different uses can be produced with different properties of the use of the advantages of white latex. In this paper, the development of a high bond strength, water resistance of good environmental water-based adhesive discussed that the vinyl acetate monomers, persulfate as the initiator, environmental synthesis of water-soluble white emulsion process. The experiment indicates that the manufacturing capacity of water-soluble adhesive white latex good experiment by the amount of initiator, the reaction temperature, reaction time, pH and monomer ratio, and a better preparation conditions : temperature 70 ± 2℃; initiator 4.7%; the best time to 50 ~ 70 min. At this point the basic products in line with the requirements of the color products as white, viscous liquids, which have a certain viscosity, But a little odor stimulation, the need for improvement. Keywords : polyvinyl acetate; Polymerization; Green 聚醋酸乙烯酯白乳胶的合成工艺 及性能研究 前 言 聚醋酸乙烯胶粘剂是由醋酸乙烯酯经自由基聚合生成的一种高分子化合物，它无毒、无味，很柔软，对很多材料都具有良好的粘结性能。早期使用的聚醋酸乙烯酯一般为均聚乳液，具有价格低廉、生产方便、粘接强度高、无毒等特点