有机化学Chapter 2. Alkanes 烷烃.ppt

Torisonal Strain(扭转张力 or 排斥力) Van der Waals Radius (范德华半径与范德华张力) In a molecular crystal, One-half the distance between two atoms of an element that are as close to each other as possible without being formally bonded to each other except for van der Waals forces. 2. Conformational Analysis of Butane Rotation about C2－C3 bond in butane 对位交叉 部分重叠 部分交叉 全重叠 全重叠 对位交叉 Stability: 部分交叉 部分重叠 2.5.2 Conformation of Cyclohexane 1. Cis-trans isomerism in Cyclohexane Ex. 1,2-Dimethylcyclopentane: The rotation is limited by “rigid” ring Stereoisomers: trans- cis- The same constituti