用化学气相沉积法(CVD)制备碳基纳米管及导电性的要点.docVIP

毕 业 论 文 题 目：用化学气相沉积法（CVD）制备 碳基纳米管及导电性的研究 学 院： 物理与电子工程学院 专 业： 物理学 学生姓名： 秦向南 学 号： 201172010333 指导教师： 王涛 日 期： 二零一五年四月 摘 要 纳米材料被誉为21世纪的重要材料。碳纳米管(CNTs)自1991年被发现以来，这种新型一维纳米材料由于具有许多优异的性质和潜在的广阔的应用前景，已成为物理、化学和材料领域的研究前沿。本论文依据目前碳纳米材料的研究发展现状，阐述了碳纳米材料研究制备中所采用的方法，并对其制备的碳纳米的应用范围进行了初步探讨，并着重开展了用化学气相沉积法制备碳纳米管的研究，同时阐述了我们团队用化学气相沉积法制备碳纤维／碳基纳米管的实验过程并对碳纤维／碳基纳米管的导电性及弯曲程度下的电阻变化进行了实验。本文实验结果对于扩大CVD法制备CNTAs的规模、推动CNTAs的应用研究，具有非常重要的实际意义及一定的理论意义。 关键词：碳纳米管；生长机理；制备方法；化学气相沉积法；导电性。 目 录 0 引言························································1 1 碳基纳米管简介··············································2 1.1 碳基纳米管··············································2 1.1.1 发现历史············································2 1.1.2 结构特征············································3 1.1.3 分类················································4 1.1.4 性质················································4 1.2 碳基纳米管的生长机理····································6 1.2.1 顶部生长机理········································6 1.2.2 底部生长机理········································6 2 纳米管的制备方法············································7 2.1 电弧放电法··············································7 2.2 等离子体法··············································8 2.3 激光蒸发法··············································8 2.4 催化裂解法··············································9 2.5 化学气相沉积法··········································9 3用CVD制备碳纤维／碳基纳米管及导电性的研究··················13 3.1用CVD制备碳纤维／碳基纳米管的过程 ······················13 3.1.1实验材料·············································13 3.1.2实验设备·············································14 3.1.3纳米纤维／碳基纳米管的制备···························15 3.2研究碳纤维／碳基纳米管的导电性及弯曲程度下的电阻变化·····16 3.2.1研究碳纤维／碳基纳米管的导电性·······················16 3.2.2研究碳纤维／碳基纳米管在不同弯曲程度下电阻的变化·····17 4 小结···················································