201601171-淮南市大气颗粒物水溶性离子..docxVIP

淮南市大气颗粒物水溶性离子粒径分布特征及来源解析杨叶1郑刘根1* 程桦1安徽大学资源与环境工程学院，矿山环境修复与湿地生态安全协同创新中心，安徽合肥，230601)摘要为了研究淮南市大气颗粒物中水溶性离子时空及粒径分布特征，于2014年7月和2015年1月分别在淮南市居民区、文教区、采矿区、工业区、商业区、山南新区采集大气颗粒物样品，并测试分析了其水溶性离子组成。结果表明：（1）大气颗粒物夏季粗、细粒子中ρ（TWSI）（TWSI为总水溶性无机离子）平均值分别为（13.44±4.53）和（27.80±17.65）μg·m-3；冬季值为（12.88±8.37）和（85.07±35.41）μg·m-3；（2）化工区和采矿区污染较为严重，主要水溶性离子（Ca2+、NO3-和SO42-）分别占夏季PM2.5中ρ（TWSI）的94%和95%，是山南新区的4~6倍；（3）大气颗粒物中TWSI主要来源于土壤源、工业污染及二次转化，其中土壤源对粗细粒子均有较大贡献；（4）冬季二次污染源主要以流动源污染为主，而夏季流动源污染和固定源污染贡献接近。关键词水溶性离子；粒径分布；来源解析Size Distributions and Sources of Water Soluble Inorganic Ion in AerosolParticles in HuainanYANG ye1 ZHENG liugen1* CHENG hua1 (1. School of Resources and Environmental Engineering, Collaborative Innovation Center for Mines Environmental Remediation and Wetland Ecological Security. Anhui University, Hefei 230601, China)Abstract To investigate the size distributions of water solubleinorganic ions, size-segregated aerosol samples were collected in six different functional areas including commercial area, cultural area, industry area, residential area, mining area and control area in Huainan city during July 2014 and January 2015. The results showed that: The average concentrations of water soluble ions of PM2.5 and PM2.5-10 was（13.44±4.53）and（27.80±17.65）μg·m-3 in summer, and was（12.88±8.37）and（85.07±35.41）μg·m-3 in winter. Ca2+、NO3-and SO42- in industry area and mining area contributed 94% and 95% of mass concentrations of the total ions in PM2.5 of summer, which is 4~6 times as much as that in control area. Source analyses indicated that the soil emissions, industrial emissions and secondary formation. NO3-and SO42- came from secondary chemical reactions of NOx and SO2, and these precursors mostly came from fossil fuel in summer while equally came from automobile exhaust and fossil fuel in winter.Key words water-soluble-ions; size distribution; source apportionment大气气溶胶在全球气候变化中起到至关重要的作用，作为云凝结核或冰核，其直接影响地球的辐射平衡，间接改变云降水性质，危害大气环境和人类健康[1]。水溶性无机离子（WSIIs）是大气气溶胶的重要组成部分，尤其是细颗粒物，研究表明，PM2.5中50%~6