石墨烯的透射电子显微镜研究.pptVIP

Basically, TEM has two working modes, the diffraction mode and the imaging mode. in the diffraction modes, the diffraction pattern can be seen as a magnified view of a planar section through the reciprocal lattice of the specimen. the section plane is normal to the incident beam. in the imaging mode, we have amplitude contrast and phase contrast. atomic scale resolution can be achieved by phase contrast. Ok, now I will introduce how scientists use TEM to determine the structure of graphene. The blue planes indicate a diffraction pattern that would be obtained at normal incidence. the red plane for tilt angle of 20°. For two (or more) layers, an additional modulation appears. As a consequence, variations of a few degrees in the tilt angle lead to strong variations in the diffraction intensities for all multi-layer samples independent of the stacking sequence, which allows a direct and unambiguous identification of single- vs. multi-layer samples. Structure Determination of Graphene by TEM XIAO Gaobo Outline Brief introduction about graphene Review of TEM How scientists use TEM to study the structure of graphene Summary Graphene is a one-atom-thick planar sheet of sp2-bonded carbon atoms that are densely packed in a honeycomb crystal lattice. Molecular structure of graphene High resolution transmission electron microscope images of graphene Graphene is as the strongest material ever measured, some 200 times stronger than structural steel Electrical conductivity 97.7 % transmittance of white light Thermal conductivity Outline Brief introduction about graphene Review of TEM How scientists use TEM to study the structure of graphene Summary TEM - Transmission electron microscope Working modes of TEM Diffraction mode Imaging mode 1 Amplitude contrast A) mass/thickness B) diffraction 2 Phase contrast Diffraction mode For a thin sheet of single crystal, its reciprocal lattice is a set of parallel rods For polyc