郑州大学有机化学8卤代烃金属有机化合物概论.ppt

* * * * * * * 炔基钠已学习 * * * * * 苯炔非常活泼。常用呋喃捕捉苯炔 8 * * * * * * 8.9 Organozinc Reagents (有机锌试剂) Simmons-Smith reaction stereospecific 8.10 Organosodium Reagents (有机钠试剂) Würtz反应 an antifungal(抗真菌的) compound isolated from lily plants 3-甲基-1,5-二甲氧基-2,4-二氯苯 2,4-dichloro-1,5-dimethoxy-3-methylbenzene Chlortetracycline 氯四环素 Thyroxine 甲状腺素 Aryl Halides(芳基卤，卤代芳烃) 8.11 Structure 8.12 Preparation Halogenation of arenes(芳烃的卤化) Halogenation of aryl diazonium salts (重氮盐的卤化) SN1 CuCl CuBr KI NaBF4 8.13 Reactions 8.13.2 Formation of Organometallic Reagents (有机金属试剂) 8.13.1 Electrophilic aromatic substitutio