[高三化学中国国家集训队上课课件3_Metathesis.ppt

Organo-transition Metal Chemistry Olefin Metathesis Representative Catalysts Developments in Catalyst Categories of Metathesis Events Engineering the Direction of the Equilibrium for Ring Closing Metathesis Factors Affecting RCM Substitution Effects on RCM:A Comparison of Catalysts RCM: An Invaluable Tool for Generation of Cyclic Structures in TOS ROM/Double RCM 1 ROM/Double RCM or RCM ROM/RCM 2 ROM/Double RCM 3 RCM: Macrocycle Synthesis En Masse Generation of Macrocycles Using Conformational Analysis En Masse Generation of Macrocycles Using Conformational Analysis Cross Metathesis 1 Cross Metathesis 2 Enyne Metathesis Tandem Dienyne RCM 2 Enyne-CM/RCM/DA Macro-Enyne-RCM 1  Type II Diene Formation Macro-Enyne-RCM 2 Transannular Diels-Alder Reaction Diyne Metathesis Diyne Macro-RCM RCM-Heck Reaction Tandem Heck-RCM Combination of Enyne-RCM with Intermolecular Diels-Alder Reaction Shair. M. D. et al, unpublished 更多资源 Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile . Copyright 2004-2011 Aspose Pty Ltd. Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile . Copyright 2004-2011 Aspose Pty Ltd. Alkyne RCM in combination with Lindlar partial hydrogenation is a selective way to generate macrocyclic (Z)-olefins Catalyst (Schrock alkylidyne complex) Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile . Copyright 2004-2011 Aspose Pty Ltd. Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile . Copyright 2004-2011 Aspose Pty Ltd. Furstner. A. et al J. Am. Chem. Soc. 1999, 121. 11108 Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile . Copyright 2004-2011 Aspose Pty Ltd. Evaluation only. Created with Aspose.Slides for .NET 3.5 Client Profile . Copyright 2004-2011 Aspose Pty Ltd. Tandem AA and RO-RCM Blechert. S. et al. J. Am. Chem. Soc. 2000, 122, 9584 Sequential Pd-catalyzed asymmetric allylic alkylation followed by ROM/RCM Evaluation only. Created with Aspose.Slid