ppt课件-arsenicimmobilizationbycalciumarsenateformation.pptVIP

Arsenic Immobilization by Calcium Arsenate Formation Paper by James V. Bothe , JR and Paul W.Brown Present by Bo-Chou, Lin Professor : J.F.Gaillard February 24 , 2000 * * Introduction * Arsenic is of environmental concern due to its toxic properties , toxicity : Arsine Arsenite Arsenoxide Arsenates Arsenic * A common method to remove dissolved arsenic in the aresenic- containing watses is though precipitation of low solubility cacium arsenates * The role of calcium arsenate formation in reducing the concentrations of dissolved arsenic has not been well established Objective of the paper * Identify those calcium arsenates, including the apatite Ca5(AsO4)3OH * Establish the conditions under which they are stable * Establish the processes responsible for the immobilization of arsenic in the presence of lime Apatites * Apatites are a class of minerals that are compositionally varied but share the same crystal structure and have been investigated as host materials for long-term immobilization of a number of environmentally hazardous elements * Apatites are attractive hosts because they tend to be stable over broad ranges of pH. Experimental Procedure * Prepare suspensions made by mixing Ca(OH)2 powder with arsenic acid and deionized water at a liquid to solids weight ratio of approximately 10 to attain molar Ca/As ratios varying from 0.80 to 4.0. * Analyze the PH and concentration of Ca and As of the solution . * Analyze the solid-phase by x-ray diffractometer , SEM and TGA Analyze Result Ca4(OH)2(AsO4)2*4H2O X-ray diffraction pattern SEM micrograph X-ray diffraction pattern for Ca3(AsO4)2*2/3H2O and Ca3(AsO4)2*1/4H2O (a) Ca3(AsO4)2*2/3H2O made with the calcium source containing 0.5 wt % magnesium (b) Ca3(AsO4)2*1/4H2O made with the calcium source containing 0.5 wt % magnesium (c) Ca3(AsO4)2*1/4H2O made with the ultrap