催化功能材料 4.经典实例[精选].pptVIP

Three types of Ziegler-Natta catalysts are currently employed: Solid and supported catalysts based on titanium compounds used in combination with cocatalysts (organoaluminum compounds). Metallocene catalysts, combination of various mono- and bis-metallocene, in particular ansa- (or bridged) metallocene complexes of Ti, Zr or Hf. They are usually used in polymerization reactions in combination with a different organoaluminum cocatalyst, methylaluminoxane (or methylalumoxane, MAO). Post-metallocene catalysts [后茂金属催化剂 ] based on complexes of various transition metals with multidentate oxy