火电厂烟气酸露点的研究综述.docxVIP

全国电力行业CFB机组技术交流服务协作网第十一届年会协奇崔 暨第三届中国循环流化床燃烧理论与技术学术会议汜义果研究与综述火电厂烟气酸露点的研究综述向柏祥杨海瑞张缦张海吕俊复(清华大学热能工程系，热能工程研究所，北京100084)摘要：电站锅炉的最大热损失是排烟热损失，约占50％以上，排烟温度每提高15—20C锅炉的热 效率大约降低1％左右，因而降低排烟温度，减少排烟热损失，对于提高锅炉效率进而提高电厂总发电效 率有重要作用【l】。然而如果排烟温度过低，甚至低于烟气的酸露点则不仅造成锅炉尾部烟道金属受热面 的严重腐蚀，甚至烟气中的飞灰跟结露的酸液形成粘稠物，造成空气预热器阻塞。酸露点指烟气中的氧 化硫与水蒸汽结合形成的硫酸蒸汽刚刚开始凝结时的温度[2】。考虑到酸露点不仅关系到锅炉厂的设计以 及安全运行，更是对电站锅炉的节能减排工作有重要的意义，因而锅炉烟气酸露点的影响因素和计算方 法的研究，已经成为国内外很多专家、学者以及研究机构的热门课题。目前常用的酸露点计算方法包括，前苏联1973年《锅炉机组热力计算标准方法》经验公式、穆勒曲 线拟合公式、Hal stead曲线拟合公式、A．G．0kkes公式、美国VerhoffBranchero估算公式、日本电 力研究所估算公式、合实验常数的估算公式、Haase＆Borgmann估算公式以及Bapahoba公式等。正文 部分首先对酸露点、酸露点的影响因素等进行介绍，然后对以上酸露点计算公式一一介绍，并对所有方 法进行分析对比，最后提出作者的观点和想法。关键词：酸露点；三氧化硫；水蒸气；计算方法Review of calculation methods of acid dew point of flue gasXlANG BaixiangLV JunfuYang Hairui(Department of Thermal Engineering，Tsinghua University,Beijing 100084,China)Abstract：Heat loss of flue gas is the maximum heat loss ofpower plant boilers，accounting for about 50％．The thermal efficiency ofboilers decreased about 1％，when the temperature offlue gas is increased every 15～20℃． And so，reducing the temperature of flue gases and the heat loss of flue gases is playing important role inimproving the thermal efficiency of boilers and the total efficiency of power plant[1]．However,if the temperature of flue gas is too low,even lower than the acid dew point of flue gas，not only is the metal heatingsurface of the rear of the boilers corroded and even the fly ash of the flue gas and acid liquor combine to form viscous material to obstruct the air preheater．111e acid dew point is the temperature when the acid vapor which is formed by sulfur oxides and vapor of flue gases just starts to condense with the decreasing temperature of fluegases【2】．111e Study of the impact factors and the calculation methods of flue gases has become a hot topic for many domestic and foreign experts，scholars and research institutions，be虻ause acid dew po谳is not only related to the design work and safe operation of boilers，als