Transformation Mechanism of Nitrobenzene in Groundwater and Soil and its Simulation and Forecast.docVIP

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2017-01-23 发布于北京
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Transformation Mechanism of Nitrobenzene in Groundwater and Soil and its Simulation and Forecast.doc

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Transformation Mechanism of Nitrobenzene in Groundwater and Soil and its Simulation and Forecast 　　Abstract： Through indoor simulation experiment， this paper determines the main factors influenced the migration and transformation in aquifer， and calculate the influence degree of these factors by analytic method. Research shows that the adsorption capacity of nitrobenzene in silt medium greater than in sand medium， the block coefficient of silt medium was 2.22， block coefficient and sand medium was 1.74. Based on the first-order kinetic equation， respective of silt medium natural decay rate constant is 0.0644/h， sand medium natural decay rate constant is 0.0056/h. 　　Keywords： Nitrobenzene； Soil； Ultrasonic Extraction； Residue Dynamics 　　0 Introduction 　　Nitrobenzene is carcinogenic， mutagenic toxic organic pollutants， which is listed as the EPA， the EC and Chinas environmental priority pollutants. As a defense， printing， plastics， pesticides and pharmaceutical raw materials and intermediates， mass production and widespread application of nitrobenzene caused serious pollution to the environment. currently， nitrobenzene adsorption studies focused on agricultural soil， forest soil by surfactant-modified soil or marine sediments， its environment the distribution， migration and transformation as well as harm the environment today is one of the hot scientific basic research. 　　Many data show that only accurate grasp of nitrobenzene features and changes affecting their respective environmental factors， in order to make a scientific assessment of nitrobenzene in the environment， transport and transformation processes and destination. To this end， the international community in many developed countries have invested a lot of manpower， material and characteristics of nitrobenzene， all aspects of pollution status， environmental transport and transformation behavior， ecological toxicity carried out basic and applied research [2]， including nitro volatilization of benzen