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a s s i g n m e n t s- california state university, northridge(s s i g n m e n t s -加州州立大学北岭)
Part 1: Acids Bases
(AP Chemistry)
Questions by Miha Lee
Corrected by Jay Stern but he didn’t give me the score.
Instructions: Classify each of the following questions as being either: Knowledge, Comprehension, Application, Analysis, Synthesis or Evaluation.
Type of Reasoning Question Knowledge
Which of the following is not a definition of an acid?
any chemical compound that, when dissolved in water, gives a solution with a pH less than 7.0.
a compound which donates a hydrogen ion (H+) to another compound.
An aqueous solution that has more hydroxide ions than hydrogen ions.
an acid is a substance that increases the concentration of hydronium ion (H3O+) when dissolved in water.
Answer) c
An acidic solution has more hydrogen ions than hydroxide ions.
Comprehension
Explain why the pH scale of a water solution at 25(C ranges from 0 to 14.
Answer) According to Arrehnius definition, an acid is a substance that increases the concentration of hydronium ion (H3O+) when dissolved in water, while bases are substances that increase the concentration of hydroxide ions (OH-). On the other hand, water has an ion product equilibrium constant (Kw) of 1.4 X 10-14 at 25(C. The pH is the negative log of the concentration of H+. pH = -log[H+] To keep the ion product equilibrium constant of water (Kw), the concentration of H+ can change only in a range from 1 to 10-14. Therefore, the pH values can be only form 0 to 14.
(I don’t agree with the answer as written. The equilibrium constant needs better explanation. For example, The equilibrium constant for water is 1.8 x 10 –16 because in pure water it is calculated from the mole concentration of water or about 55.6 moles/liter. The activity of the water is the amount that self-ionizes. Based on resistivity measurements of pure water, this is approximately 1 x 10 –7 for each of the hydrogen ion concentration and hydroxyl ion concentration. Then Kw = Keq [H2O] = [H+][OH-] = 1.0 x 10-14. That is, the concentration
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