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Synthesis and Superconductor Properties of
Bi2.1Sr1.9 CaCu2Ox-BaZrO3 Composite Powder
Received: 13/10/2002 Accepted : 2/6/2003
MANASREH W.A *
Introduction
Pinning of superconducting current magnetic vortices at the superconducting matrix inhomogenities is widely used for the enhancement of critical current density Jc at high temperatures. This problem is most actual for Bi-2223 and Bi-2212, which is due to their high flexibility and ability to texture, and more interesting to be used as long-length wires and tapes [1].
One type of such inhomogenities is a second phase inclusions in the matrix. They may be formed by deviation from superconducting phase stoichiometry
* Department of Chemistry, Faculty of Science, Mutah University, Jordan.
[2], solid solutions annealing beyond the singel phase area [3-5], and introduction of elements different from the elements of superconducting system [3,6-8]. In the later, the additional phase must be compatible with the superconductor under its synthesis conditions and must not deteriorate its superconducting properties.
BaZrO3 is thermodinamically stable compound, and its introduction into Y-123 results in a critical current density enhancement [9]. Data obtained by reference 10, confirms almost total absence of BaZrO3 interaction with Bi-2223. It is known that SrZrO3 is one of the phases compatible with Bi-2212 and its addition leads to critical current density increase and does not influence the superconduter transition temperature (Tc)[8]. At the same time there is no data for BaZrO3 regarding compatibility or incompatibility with Bi-2212. This work investigates the possibility of using BaZrO3 as a pinning additive in Bi-2212.
Experiment
Bi-2212 (Bi2.1Sr1.9CaCu2Ox) was prepared by evaporation of corresponding nitrates solution in 5N nitric acid and decomposition of the obtained mixture in alund crucible at t
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