physic chemistry.pptVIP

Non-expansion work done by the surroundings increases Gibbs energy and this non-expansion work is related to chemical potential. In the same way, U=f(S, V, n1,n2，……，nk) (μB: chemical potential) If H=f(S, P, n1,n2，……，nk) And if A=f(T, V, n1,n2，……，nk) b. Definition Notice: The partial molar quantity is defined at constant T and P, whereas chemical potential is defined at constant particular independent variables. They are different, only the partial molar Gibbs energy is exactly equal to chemical p