焦炉煤气制甲醇的工艺技术研究.doc

焦炉煤气制甲醇的工艺技术研究 2012-08-18 11:11:30| 分类： HYPERLINK /liuhewei1314521@126/blog/#m=0t=1c=fks_084071082081087075085080085095085085087071084084095074080煤化工资料|字号 订阅 摘要：焦炉煤气制甲醇的关键技术是净化脱硫与烷烃转化。脱除噻吩、硫醚、硫醇类有机硫是干法脱硫的主要目标，加氢转化有机硫并防止发生甲烷化副反应是加氢转化脱硫的技术难点，组合式两级转化、两级吸收是精脱高浓度有机硫的优选方案。催化部分氧化工艺是目前焦炉煤气烷烃转化的主要技术手段。及时移走反应热以防止合成催化剂过热失活同时副产高品质蒸汽是甲醇合成反应器的基本技术要求。低压法合成甲醇催化剂的活性与选择性是决定甲醇合成效率和副反应产率的关键。 关键词：焦炉煤气；净化脱硫；催化转化；氢碳比；催化剂；甲醇合成；甲醇精馏 Study on Methanol Production Technology from Coke Oven Gas WU Chuang-ming Abstract：Purification desulfurization and alkane conversion are crucial technologies for methanol production from coke oven gas. The removal of organic sulfur such as thiofuran，thioether and mercaptan is the main objective of dry desulfurization，and hydroconversion of organic sulfur and preventing the methanation side reaction are the technological difficulties of hydroconversion desulfurization. The combination of two-level conversion and two.1evel absorption is the preferential scheme for refined removal of high-concentration organic sulfur. The catalytic partial oxidation process is now the main technology method for conversion of alkane in coke oven gas. The basic technical requirement for methanol synthesis reactor is moving reaction heat in time to prevent the synthetic catalyst from superheating and being inactivated，and meanwhile byproducing the high quality steam. The activity and selectivity of catalyst for synthesizing methanol under low pressure are the crucial factors to determine the methanol synthesis efficiency and the side reaction rate. Key words：coke oven gas；purification desulfurization；catalytic conversion；hydrogen/carbon ratio；catalyst；methanol synthesis；methanol distillation 近年来，随着钢铁工业对焦炭的巨大需求而高速发展起来的炼焦产业，在焦炭产能无序扩张、产量大幅度增长的同时，副产的大量焦炉煤气导致了焦炭产区的环境急剧恶化，不少单一炼焦的独立焦化企业“只焦不化”，对大量炼焦剩余的焦炉煤气采取点天灯方式燃烧排空，既严重污染环境，又造成资源浪费。作为贫油、缺气的能源需求大国，充分、合理利用大量点天灯外排的焦炉煤气，对建设资源节源型社会，实现经济可持续发展具有重要意义。 1 焦炉煤气的利用途径 ① 焦炉煤气的组成与杂质含量 焦炉煤气的主要组分为H2、CO、CH4、CO2等随着炼焦配比和操作工艺参数的不同，焦炉煤气的组成略有变化。一般焦炉煤气的组成