利用零价铁金属及铁铝复合金属还原水中六价铬之研究.doc

利用零價鐵金屬及鐵鋁複合金屬還原水中六價鉻之研究 Comparison of Zero-Valent Iron and Bimetallic Iron-Aluminum on the Reduction of Aqueous Hexavalent Chromium 研究生：陳泰宇 Tai-Yu Chen 指導教授：黃益助 Yi-Chu Huang 【摘要】 近年來台灣地區因工業的迅速發展，相對的衍生出許多環境污染物。重金屬鉻常被使用於工業製程中，例如顏料塗料，耐火材料、電鍍業、金屬加工業以及皮革製造業，重金屬鉻皆為主要之原料。含鉻化合物為具有致畸胎性以及致癌性之毒性物質，目前的工業廢水中，電鍍廢水佔約5~10%，而這些廢水若處理不當，將會對環境造成極大的危害。 本研究以零價鐵及鐵鋁複合金屬水中六價鉻還原研究分別以微米鐵、奈米鐵與鐵鋁複合金屬，進行水水中六價鉻之還原實驗，使其由毒性較高的六價鉻，還原成毒性較低的三價鉻，並探討零價鐵還原六價鉻的各項影響參數。操作參數包括起始pH值、零價鐵鐵鋁複合金屬粒徑、零價鐵、零價鐵六價鉻之量比(Fe/Cr6+)、鐵鋁複合金屬六價鉻之量比(Fe/Cr6+)以及鐵鋁複合金屬之含鐵量等。零價鐵零價鐵零價鐵及鐵鋁複合金屬零價鐵鐵鋁六價鉻鐵鋁零價鐵零價鐵鐵零價鐵及鐵鋁複合金屬鐵鋁複合金屬六價鉻鐵鋁鐵鐵鋁鐵六價鉻鐵鋁鐵鋁鐵鐵鋁鐵鐵鋁 關鍵字：三價鉻六價鉻零價鐵鐵鋁複合金屬Due to the rapid industrial development, many pollutants were produced in recent years. Chromium is a raw materials and often used in the industrial manufacturing process such as pigment, paint, fireproofing materials, electroplating, metal processing, and tanning, etc. Chromic compounds, which are toxic to human health, are considered to be the teratogenic and carcinogenic substances. Electroplating wastewater accounts for about 5 to 10 percent volumes of all industrial wastewater. If the wastewater is not properly handled and processed, it may bring about enormous impairments to the environment. In this study, zero-valent iron (Fe0) including micro-scale and nano-scale iron, and bimetallic iron-aluminum (Fe-Al) were utilized to reduce the hexavalent chromium (Cr6+) to the trivalent chromium (Cr3+) which is a less toxic from of chromic compound. The parameters concerned in this study included initial pH value, particle size of Fe0 and Fe-Al, pretreatment of acid-washing process, dosage ratio between Fe0 and Cr6+ (Fe/Cr6+), dosage ratio between Fe-Al and Cr6+ (Fe-Al/Cr6+), and iron contents of Fe-Al. The result shows that acid-washing pretreatment could remove the impurities which were adsorbed by iron particle, and then enhanced the reaction rate. From the characteristic analysis, the surface area of Fe0 was reciprocally proportional to particle size but was dir