Chapt 12 carbonyl compound.ppt

羧酸及其衍生物 A great many carboxylic acids are found in nature acetic acid, CH3CO2H vinegar 2010.10： 2.9万吨（我国） butanoic acid，CH3CH2CH2CO2H， odor of sour butter。 hexanoic acid，CH3(CH2)4C02H，unmistakable aroma of goats and dirty gym socks。 palmitic acid , CH3(CH2)14CO2H,软质酸， 普通命名应用很普遍 Common Name of Some Carboxylic Acid and Acyl Groups 系统命名法命名下列化合物 羧酸的光谱性质 对比苯甲醇和苯甲醛 苯甲醇 苯 酚 1H NMR谱 苯甲酸的羧基氢吸收峰位于12.0 ppm附近。而醛羰基氢原子的吸收峰位于9.0-10.0左右，单峰。 苯甲醇 Acidity of Some Carboxylic Acids Carboxylic acids are weak acids Why are carboxylic acids so much more acidic than alcohols Substituent Effects on Acidity Substitue