材料热力学-第六章.ppt

第六章 Phase Equilibria Introduction General Concepts Phase diagrams of pure substances Multicomponent system Phase diagrams of solution General Concepts Phase Phase Transformation Phase Transformation Enthalpy and Entropy of a Transition Enthalpy and Entropy of a Transition Entropy and Enthalpy of Transition Phase Transformation Phase Diagrams Phase Equilibria Phase Equilibria Phase diagrams of pure substances Phase diagrams of pure substances Phase diagrams of pure substances Phase diagrams of pure substances Phase diagrams of pure substances Phase diagrams of pure substances Phase diagrams of pure substances Phase diagrams of pure substances Gibbs Phase Rule Gibbs Phase Rule Gibbs Phase Rule Gibbs Phase Rule Gibbs Phase Rule Claussius Clapeyron Equation Claussius Clapeyron Equation Claussius Clapeyron Equation Gibbs Phase Rule Partial Molar Properties Partial Molar Properties Partial Molar Properties Partial Molar Properties Partial Molar Properties Partial Molar Properties Partial Molar Properties Partial Molar Properties Partial Molar Properties Partial Molar Properties Partial Molar Properties Partial Molar Properties Gibbs-Duhem Partial Molar Properties Partial Molar Properties In order to understand the thermodynamic properties of these multicomponent systems we need to develop a method of describing the properties of mixtures. This strategy for describing mixtures is heavily based on the concept of partial molar properties. We define the partial quantity above as the quantity , which we call the partial molar property of M, This property tells us the change in the property M of the system on adding a minute amount of component i And This says that I can write the extensive properties as weighted sums of the components. It also implicitly says that not all the partial molar properties are independent. In the case of a binary solution we find that Using the above expressions for the partial molar properties of a binary mixture we have that the partial molar