含钛高炉渣论文四川某地含钛高炉渣综合利用途径研究.docVIP

含钛高炉渣论文：四川某地含钛高炉渣综合利用途径研究 【中文摘要】随着经济的持续发展和社会的不断进步,人类对各种金属的需求量越来越大,冶金规模也越来越大,由此造成了各种金属的富矿资源不断减少乃至趋于枯竭,矿产资源的供需矛盾日益突出。我国西部地区的钛铁矿经高温炼铁后排放出的废渣中含18%左右(以TiO2计)钛资源,长期以来未利用,造成资源严重浪费。并且占用土地,污染环境。因此开展工业废渣资源的综合利用技术研究,对国民经济的可持续发展及西部大开发,都有极为重要的意义。本论文以四川某地含钛高炉渣为研究对象,通过X荧光光谱分析其主要成分和矿物组成。采用粒度、水力重选、磁选等物理方法,考察钛的分离富集规律。结果表明：该尾渣为碱性渣,钛主要以钙钛矿形式存在。水力重选分选后,重矿物品位为20.76%,轻矿物品位为15.69%；磁选后,带磁性矿物品位18.98%,非磁性矿物品位为17.97%,与原矿品位18.56%相比,TiO2富集效果不明显,即通过物理法使得尾渣中钛分离富集效果不明显。采用四因素三水平正交实验,分别考察以盐酸和硫酸为浸出剂浸取含钛高炉渣时,pH值、液固比、搅拌时间、浸出温度等因素对TiO2浸出率的影响,结果表明：以盐酸和硫酸为浸出剂浸取含钛高炉渣,TiO2最高浸出率分别为65.09%和65.24%。对实验数据进行极差分析,各因素影响顺序分别是,盐酸体系：pH值温度液固比搅拌时间；硫酸体系：pH值搅拌时间液固比温度。经比较硫酸体系在能耗、时间和耗酸量等方面均优于盐酸体系。采用硫酸法制备钛白粉,通过单因素方法考察了酸浸阶段液固比、硫酸用量、浸出温度对Ti02浸出率的影响并优化了工艺条件。在pH值0.5,液固比为4.5：1,硫酸用量为95ml/100g试样,浸出温度为45℃,TiO2浸出率最高达69.71%,经洗涤后TiO2总浸出率可达89.82%。该条件下3次重复性实验中TiO2平均总浸出率为89.95%。考察水解温度和水解时间对TiO2水解率的影响。水解温度95℃,水解时间2h水解率可达96%以上。水解产物经洗涤,干燥,高温煅烧制得产品Ti02纯度为98.82%,水溶物0.6%,未过45gm标准筛矿物0.1%,达到锐钛型钛白粉主要基本指标。初步研究了以含钛高炉渣为主要原料制备的无机外墙涂料的性能。当水玻璃加入量为30%,碱(NaOH 2%, KOH 2%)加入量为4%,碱土金属氧化物加入量为5%,填料为2%,制得的外墙涂料涂膜未软化、无脱落,无刷痕、无干裂,且耐冻融循环性好。为含钛高炉渣综合利用制备无机外墙涂料提供了实验基础。 【英文摘要】With the continuous economic development and social progress, human beings have growing demand for various metal, at the same time, as the Metallurgical industry’s development, the rich ore of various Metal Resources have been reduced or even become depleted. Nowadays the conflicts of supply and demand for mineral resources are increasingly prominent. In Western China, the content of Ti-bearing Slag in waste metal residue after high-temperature ironed is about 18% (TiO2), which hasn抰 been utilized for a long time, thus causing a serious waste on resources, land as well as polluting the environment. Therefore, the study on comprehensive utilization of industrial waste residue plays a quite important role on the sustainable development of the national economy and Western Development.Research object of the paper is a titanium blast furnace residue in certain place in Sichuan, we analyze its main com