化工热力学ChVaporLiquidEquilibriumIntroduction.docVIP

Chapter 10 Vapor/Liquid Equilibrium: Introduction 10.1 THE NATURE OF EQUILIBRIUM Measures of Composition Mass fraction Mole fraction Molar concentration 10.2 THE PHASE RULE. DUHEM’S THEOREM For any closed system formed initially from given masses of prescribed chemical species, the equilibrium state is completely determined when any two independent variables are fixed. 10.4 SIMPLE MODELS FOR VAPOR/LIQUID EQUILIBRIUM Raoult’s Law Dewpoint and Bubblepoint Calculations with Raoult’s Law Engineering interest centers on dewpoint and bubblepoint calculations: BUBL P: Calculate yi and