Emission Spectra teachnlearnchem发射光谱 teachnlearnchem.pptVIP

Emission Spectra Emission Spectrum of Hydrogen Emission Spectrum of an Element Continuous and Line Spectra Continuous and Line Spectra Flame Emission Spectra Flame Tests for Certain Metals Fireworks Fireworks Composition of Fireworks Gunpowder Sulfur, charcoal, potassium nitrate (saltpeter) Salts (to give color) Red = lithium Green = copper * 1 nm = 1 x 10-9 m = “a billionth of a meter” 410 nm 434 nm 486 nm 656 nm 1 nm = 1 x 10-9 m = “a billionth of a meter” 410 nm 434 nm 486 nm 656 nm 1 nm = 1 x 10-9 m = “a billionth of a meter” 4000 A o 5000 6000 7000 light Na H Ca Hg 400 450 500 550 600 650 700 750 nm Visible spectrum l (nm) 4000 A o 5000 6000 7000 4000 A o 5000 6000 7000 light Na H Ca Hg Photographs of flame tests of burning wooden splints soaked in different salts. Include link to web page /christjs/flame%20tests.htm methane gas wooden splint strontium ion copper ion sodium ion calcium ion Copyright ? 2006 Pearson Benjamin Cummings. All rights reserved. BORAX BEAD TESTS FOR CERTAIN METALS (All beads formed in the oxidizing flame) Copyright ? 2007 Pearson Benjamin Cummings. All rights reserved. Copyright ? 2007 Pearson Benjamin Cummings. All rights reserved. Common chemicals used in the manufacture of fireworks Ammonium perchlorate aluminum Blue flame: copper carbonate, copper sulfate, or copper oxide Barium chlorate antimony sulfide Red flame: strontium nitrate or strontium carbonate Barium nitrate charcoal White flame: magnesium or aluminum Potassium chlorate magnesium Yellow flame: sodium oxalate or cryolite (Na3AlF6) Potassium nitrate sulfur Green flame: barium nitrate or barium chlorate Potassium perchlorate titanium White smoke: potassium nitrate plus sulfur Strontium nitrate Colored smoke: potassium chlorate and sulfur, plus organic dye Whistling noise: potassium benzoate or sodium sal