金属-有机配位体配合物的稳定常数.docx

?表中离子强度都是在有限的范围内，I≈0。　　金属-有机配位体配合物的稳定常数Stability Constants of Metal Ion-Organic Coordination Compounds序号(No.)　配位体(Ligand)金属离子(Metal ion)配位体数目?n(Number of ligand)　lgβn1　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　乙二胺四乙酸(EDTA)[(HOOCCH2)2NCH2]2　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　　Ag+17.32Al3+116.11Ba2+17.78Be2+19.3Bi3+122.8Ca2+111.0Cd2+116.4Co2+116.31Co3+136.0Cr3+123.0Cu2+118.7Fe2+114.83Fe3+124.23Ga3+120.25Hg2+121.80In3+124.95Li+12.79Mg2+18.64Mn2+113.8Mo(V)16.36Na+11.66Ni2+118.56Pb2+118.3Pd2+118.5Sc2+123.1Sn2+122.1Sr2+18.80Th4+123.2TiO2+117.3Tl3+122.5U4+117.50VO2+118.0Y3+118.32Zn2+116.4Zr4+119.42乙酸(Acetic acid)CH3COOHAg+1,20.73,0.64Ba2+10.41Ca2+10.6Cd2+1,2,31.5,2.3,2.4Ce3+1,2,3,41.68,2.69,3.13,3.18Co2+1,21.5,1.9Cr3+1,2,34.63,7.08,9.60Cu2+(20℃)1,22.16,3.20In3+1,2,3,43.50,5.95,7.90,9.08Mn2+1,29.84,2.06Ni2+1,21.12,1.81Pb2+1,2,3,42.52,4.0,6.4,8.5Sn2+1,2,33.3,6.0,7.3Tl3+1,2,3,46.17,11.28,15.10,18.3Zn2+11.53乙酰丙酮(Acetyl acetone)??CH3COCH2CH3Al3+(30℃)1,28.6,15.5Cd2+1,23.84,6.66Co2+1,25.40,9.54Cr2+1,25.96,11.7Cu2+1,28.27,16.34Fe2+1,25.07,8.67Fe3+1,2,311.4,22.1,26.7Hg2+221.5Mg2+1,23.65,6.27Mn2+1,24.24,7.35Mn3+33.86Ni2+(20℃)1,2,36.06,10.77,13.09Pb2+26.32Pd2+(30℃)1,216.2,27.1Th4+1,2,3,48.8,16.2,22.5,26.7Ti3+1,2,310.43,18.82,24.90V2+1,2,35.4,10.2,14.7Zn2+(30℃)1,24.98,8.81Zr4+1,2,3,48.4,16.0,23.2,30.14草酸(Oxalic acid)??HOOCCOOHAg+12.41Al3+1,2,37.26,13.0,16.3Ba2+12.31Ca2+13.0Cd2+1,23.52,5.77Co2+1,2,34.79,6.7,9.7Cu2+1,26.23,10.27Fe2+1,2,32.9,4.52,5.22Fe3+1,2,39.4,16.2,20.2Hg2+19.66Hg22+26.98Mg2+1,23.43,4.38Mn2+1,23.97,5.80Mn3+1,2,39.98,16.57,19.42Ni2+1,2,35.3,7.64,～8.5Pb2+1,24.91,6.76Sc3+1,2,3,46.86,11.31,14.32,16.70Th4+424.48Zn2+1,2,34.89,7.60,8.15Zr4+1,2,3,49.80,17.14,20.86,21.155乳酸(Lactic acid)??CH3CHOHCOOHBa2+10.64Ca2+11.42Cd2+11.70Co2+11.90Cu2+1,23.02,4.85Fe3+17.1Mg2+11.37Mn2+11.43Ni2+12.22Pb2+1,22.40,3.80Sc2+15.2Th4+15.5Zn2+1,22.20,3.756水杨酸(Salicylic acid)??C6H4(OH)COOHAl3+114.11Cd2+15.55Co2+1,26.72,11.42Cr2+1,28.4,15.3Cu2+1,210.60,18.45Fe2+1,26.55,11.25Mn2+1,25.90,9.80Ni2+1,26.95,11.75Th4+1,2