电导法测定乙酸乙酯皂化反应的速率常数数据处理.docxVIP

【数据处理】25℃的反应速率常数kT1，将实验数据及计算结果填入下表：恒温温度=24.9℃=1.994ms·cm-1V乙酸乙酯=10.00mL [乙酸乙酯]=0.0200mol/LVNaOH=10.00mL [NaOH]=0.0200mol/Lc0=0.5×0.0200=0.01mol/L实验数据记录及处理表1：t/min/ms·cm-1/ms·cm-1·min-121.8350.15907590.23506750.31906020.3920.049000101.5420.4520.045200121.490.5040.042000141.4440.550.039286161.4040.590.036875181.3680.6260.034778201.3350.6590.032950221.3060.6880.031273241.2810.7130.029708261.2590.7350.028269281.2370.7570.027036301.2170.7770.025900图1：25℃-由于第一个数据偏离其它数据太多，有明显的误差，所以舍去。数据处理：对作图,求出斜率m，并由求出速率常数.直线公式：y=16.616x + 0.7888 R2=0.9998m