溴代烷烃的臭氧消耗潜势值的计算.PDFVIP

1997 3 ENVIRONMENT AL SCIENCE M ar. , 1997 * 钟晋贤　张德强 ( , 100085) CH3Br CH2Br2 OH , CH 3Br ,ODP , CH2Br2 . , , O DP ( O DP) ; 0. 33 0. 076. , , . , ( ODP ) . ODP , Wuebbles[ 1] 1981 , , ODP . O DP X CFC-11, ,2 , ODP = O3( X) / vx O 3 ( CFC-11) / v CFC-11 ( 1) , O3( X) X , vX X , O3 ( CFC-11) CFC-11 , v CFC-11 CFC . O DP , ( ODS) , ,. CH3 Br CH2 Br 2 O D P , . 1 ODP O DP , ODP AER ( Atm ospheric and Enviro nm ent al Research Inc. ) , Du Pont ( Du Pont Cent ral Research) , L L NL ( L aw rence L ivermore Nat ional L abo - rat ory ) Oslo ( Univer sit y o f Oslo ) .[ 2- 7] [ 8] , ,, . O DP , , ,, OD P . CH3Br CH2Br2 OD P . Solo mon [ 9] P ollack [ 10] , O DPX = nX 3 M CF C-11 MX ODP X CFC -11 : FX F C FC-11 = [ BL P] [ BEF] ( 2) , nX X (3 CF C-11 ) , MX M CFC-11 X CFC-11 , X CFC-11 X CF C-11 ,X , FX / FCFC-11 X CFC-11 . , * : 1996-10-16 2 67 . BL P ( Br omine L oading P ot ent ial) , C FC -1 1 , ; BEF ( Bromine Eff iciency Factor) , CF C-11 . ( 2) ,, . , F X / FCFC-11 CH2Br2, 1. 08 , CH 3Br 0. 145[ 10] ; .[ 11] 40 - 50 A E R 2-D , BEF = 48[ 12] . , 1, CH2Br2 , CH3Br CH2Br2, 1. ( CH3Br ) = 0. 9[ 13] , 0. 75[ 11] , 2. CFC-11 =CFC-11 5 0a[ 14] , CH3Br CH2Br 2 : 1 = 1+ 1+ 1 + 1 CH3Br O H str at ocean other ( 3) , CH3Br CH3 Br , OH OH ,- OH , 1. 60a. strat ( 3 5a) [ 15] , ocean ( 3. 7a) [ 16] , ,other ,. ( 3) , 1. 08a. WM O 1995 ( 0. 7a - 1. 7a ) [ 12] , P rinn [ 17] Science =CH3Br 1. 3a OH , [ 18] 25% . O DP . CH2 Br 2, OH = 0. 29a, , CH3Br , =CH2Br2 0. 27a. 2 ODP . 1 CH3Br CH2Br2 ( 2) , 1. ODP / a BLP BEF O DP CH3Br 0. 9 1. 08 0. 0069 CH 2Br2 0. 75 0. 27 0. 0016 48 48 0. 33 0. 076 M ell ouki [ 11] ( O DP CH3Br = 0. 65, 0. 64; OD PCH2Br2 = 0. 17, 0. 13) , O DP 1, 3 : ( 1) , CH3Br CH 2Br 2 Prinn [ 17] 1995 Sci- ence OH , CH 2Br 2 1. 6a 25% , CH 3Br 0. 67a , Mellouki 1. 7a 0. 4a CH3CCl3 , 5. 7a[ 18] 4. 9a. ( 2) CH3Br CH 2Br 2 , , =occan 3. 7a , CH3Br . CH3Br CH2Br2 0. 27a, M ellouki 1. 08a . ( 3) . Mellouki CH3CCl3 ,= 1, =CH3Br 0. 9 =CH2Br2 0. 75. 1 W uebbles D J . Law rence