Newest Trend in U最新趋势.S. Disinfection EconomyQuality of .pptVIP

Designing a Bulk Sodium Hypochlorite System Presented by Patrick H. Allman III General Manager Odyssey Manufacturing Co. Disinfection Options – June 1999 Disinfection Options – June 2003 Disinfection Options – June 2005 Sodium Hypochlorite Bleach Liquid Bleach Liquid Chlorine Soda Bleach Liquor Chlorine CHEMICAL FORMULA NaOCl Manufacturing Process 2NaOH + Cl2 = NaOCl + H20 + Heat Properties of Sodium Hypochlorite Mildly Corrosive Has Free Sodium Hydroxide (Caustic Soda) pH=12.5 to 13 Pale Yellow Solution, 12.5% By Volume Non-Flammable Incompatible with Many Other Chemicals Relatively Short Shelf Life - Contaminants, Heat And UV Cause Decomposition Contrary to White’s Handbook of Chlorination One Gallon of 120 GPL or 12 Trade Percent Equals 1 lb of Cl gas BLEACH DEGRADATION Primary 3NaOCl = 2NaCl + NaClO3 (Sodium Chlorate) Secondary 2NaOCl = 2NaCl + O2 (Gassing) Factors: Heat UV (e.g., Sunlight) Impurities (Primarily Heavy Metals) Strength (Rate = K (OCl-]2 Sodium Hypochlorite Degradation – Average Manufacturer @ 70 Degrees F Time of Manufacture - 12.5 Trade Percent 2 Days Later – 12.43 Trade Percent 7 Days Later – 12.25 Trade Percent 14 Days Later – 12.01 Trade Percent 21 Days Later – 11.78 Trade Percent 28 Days Later – 11.55 Trade Percent 35 Days Later – 11.34 Trade Percent Sodium Hypochlorite Degradation – Average Manufacturer @ 80 Degrees F Time of Manufacture - 12.5 Trade Percent 2 Days Later – 12.34 Trade Percent 7 Days Later – 11.96 Trade Percent 14 Days Later – 11.47 Trade Percent 21 Days Later – 11.01 Trade Percent 28 Days Later – 10.59 Trade Percent 35 Days Later – 10.21 Trade Percent Use of Pilot or Temporary Systems To Maintain Continuous Disinfection During Conversion Construction To size pumps and bulk storage tanks To Determine Finished Water Quality To Test different types of Equipment Familiarize Operations Personnel with Sodium Hypochlorite Verify Operations in Unusual Situations Sodium Hypochlorite System Design Delivery