Thermal Analysis University of Utah热分析犹他大学.pptVIP

Thermal Analysis Terry A. Ring Chemical Engineering University of Utah Different Techniques Thermometric Titration (TT) Heat of mixing Thermal Mechanical Analysis (TMA) Thermal Expansion Coefficient Dynamic Mechanical Analysis (DMA) Viscoelastic Properties Differential Scanning Calorimetric (DSC) Heat flow during Transitions Thermal Gravimetric Analysis (TGA) Weight Loss due to decomposition Derivative Thermogravimetric Analysis (DTG) Differential Thermal Analysis (DTA) Heat of Transitions Temperature Programmed Desorption (TPD) Temperature at which gas is desorbed from (catalyst) surface Emission gas Thermoanalysis (EGT) Basic Principle Sample is heated at a constant heating rate Sample’s Property Measured Wt TGA Size TMA Heat Flow DSC Temp DTA Gas evolved TPD TGA Constant Heating Rate Initial Temp Final Temp Heating Rate (°C/min) Data Weight vs Time Weight vs Temp. Differential This Data (DTG) DSC DSC Constant Heating Rate Initial Temp Final Temp Heating Rate (°C/min) Data Heat flow to sample minus Heat flow to reference vs Time (Temp.) Measures heat of crystallization DTA Sample and Reference Placed in Heater Constant Heating Rate Initial Temp Final Temp Heating Rate (°C/min) Data Temp of Sample vs Time (or Temp) Temp of Reference vs Time (or Temp) Reference should be inert, e.g. nothing but latent heat Measures Heat of crystallization Glass Transition Temperature DTA + DTG TMA Constant Heating Rate Initial Temp Final Temp Heating Rate (°C/min) Data Size of Sample vs Time (or Temp.) Measures Thermal Expansion Coefficient Volume change on crystalization or crystal transformations Sintering Glass Transitions in Polymers TMA DMA Constant Heating Rate Initial Temp Final Temp Heating Rate (°C/min) Data Force vs Time (or Temp.) Force delay vs Time (or Temp.) Viscoelastic Properties Storage and Loss Modulus Measures Glass Transition Viscoelastic Properties We have TGA - only Heating a sample of Calcium oxalate Ca(C204)*xH2O ?? Ca(C204) *H2O + x-