LaNiO3+掺杂复合氧化物的制备及对氧的电催化性能研究.pdfVIP

G034 LaNiO 掺杂复合氧化物的制备及对氧的电催化性能研 3 究 王先友? 黄伟国 汪形艳 李俊 王希敏 （湘潭大学化学学院，湖南湘潭 411105 ） 摘 要 采用溶胶-凝胶法制备了系列 La Sr Ni Mn O (0≤x≤0.3, 0≤y≤0.5)钙钛矿型复合氧 1-x x 1-y y 3 化物，并用活性炭作载体制备空气电极。用X-射线衍射（XRD）对样品进行形结构分析，用扫描 电镜（SEM）观察形貌，测试表明样品为六方晶系的钙钛矿结构。电化学测试采用三电极体系， 通过小幅度三角波电位伏安法测试了多孔电极的表面粗糙因子（Rf），阴极极化和阳极极化的稳 态极化曲线及循环伏安法进行了电化学性能测试。结果表明，通过 B 位掺杂 Mn 及继续在 A 位掺 杂Sr可明显的改善LaNiO3 催化剂对氧还原和析氧的电催化性能，电极有较好的稳定性。 关键词 电催化性能 氧电极 钙钛矿型氧化物 氧还原 析氧 STUDIES OF PREPARAENT AND ELECTROCATALYSTIC PROPERTY OF DOPED LaNiO3 PEROVSKITE OXIDES FOR OXYGEN ELECTRODE HUANG Wei-Guo, WANG Xian-You, WANG Xing-Yan, Li Jun and WANG Xi-Min (College of Chemistry, Xiangtan University, Hunan 411105,China) Abstract The perovskite oxides, La Sr Ni Mn O (0 ≤x ≤0.3, 0 ≤y ≤0.5) were prepared by 1-x x 1-y y 3 a sol-gel route from the constituent metal nitrates and citric acid. The single-phase oxides were characterized by X-ray diffraction (XRD) and the lattice parameters d were evaluated. Intensities of capacitive currents from cyclic voltammemtry measurements were used to estimate the porous electrodes roughness factor, Rf. The electrochemical studies of mixed oxides electrode were measured by linear sweep voltammemtry. Results indicated that the electrocatalystic properties of LaNiO3 for oxygen reduction and oxygen evolution reactions were improved by doping the B ions or A ions, and this kind of material was a promising catalytic materials for oxygen electrode. Key words electrocatalystic property, oxygen electrode, perovskite oxide, oxygen reduction reaction, oxygen evolution reaction. 引 言 稀土过渡金属钙钛矿型复合氧化物（ABO 型）是目前研究较多的新型固体材料之一[1-4]， 3 此类化合物由于结构的特