纳米TiO2在竹材表面的自组装及其防腐性能研究孙丰波江泽慧余雁.doc

纳米TiO2及能研究 孙丰波 江泽慧* 余 雁（1.国际竹藤网络中心 北京 100102）摘 要：竹材是一种重要的森林资源，但容易腐朽，在户外使用受到限制。本文采用溶胶-凝胶法，在低温条件下制备了TiO2溶胶，并通过浸渍提拉的方式，完成了竹材的TiO2改性。同时利用电子核磁共振波谱仪(NMR)、场发射环境扫描电镜(FESEM)、X射线衍射仪(XRD)、X射线能谱仪(EDAX)对TiO2进行形态和结构表征，重点研究了TiO2对竹材防腐性能的影响。研究结果表明， TiO2改性竹材不仅完全保持了竹材的天然颜色、纹理、结构，而且抗菌性能由不具抗菌性变为对大肠杆菌的杀菌率超过99%，防霉性能提高了10倍。竹材功能性改良新手段，关键词：竹材 TiO2 纳米薄膜 抗菌 防霉Modification of nano TiO2 on Bamboo and its antibacterial and mildew resistance Performance Jiang Zehui1 Sun Fengbo1 Yu Yan1* Ren Haiqing2 Wang Ge1 Liu Xinge1 (1. The International Center for Bamboo and Rattan Beijing 100102；2. Research Institute of Wood Industry, Chinese Academy of Forestry Beijing 100091) Abstract: Bamboo, a kind of forest resources only less important than wood, is especially easy to mildew and mouldy during outdoor service. In this work, TiO2 sols were synthesized under low-temperature condition by sol-gel method. The crystalline TiO2 film was coated on the bamboo at low temperature. The TiO2 films were characterized by nuclear magnetic resonance spectrometer (NMR), field emission scanning electron microscope (FESEM), X-ray diffraction (XRD) and energy dispersive X-ray analysis (EDAX). The results showed that: modified bamboo was mainly covered with anatase nano TiO2 film. The nano- TiO2-modified bamboo maintained the natural wood color, texture, structure, improved its anti-bacterial property from non-anti-bacterial to Anti-Escherichia coli, and the bactericidal rate reached over 99%. Meanwhile its mildew resistance property increased over 10 times. So this method is expected to became the new way of functional improvement on bamboo, and it had the reference meaning for the protection and improvement of wood and other biologic materials. Key Word: Bamboo, TiO2, nano film, antibacterial, mildew resistance 竹子是一种重要的森林资源，其生长周期短，可再生性强，是当前缓解木材供需矛盾的理想替代资源。然而，竹材含有丰富的营养物质，如淀粉、蛋白质等，在适当的环境条件下，很容易产生腐朽、霉变[]，极大地限制了它的应用范围和效果。目前，通过表面涂饰、热处理、化学药剂浸注等传统物理化学手段对竹材进行防护，取得了一些有意义的成果，但是至今没有一种方法能在不改变竹材本色的情况下，兼顾性能、成本及环境友好三个重要评价指