乳胶粒粒径对丙烯酸酯压敏胶粘剂性能的影响+.pdf

647 [1] [2-7] P(BA-co-AA) 1.1 (BA) (AA) (DIW) 1.2 P(BA-co-AA) 2L 1h 3h 50% P(BA-co-AA) (PET) (MA Series) (CTA) (MA) (BA) N2 75oC (MA) (BA) (AA) (CTA) 1h 30min pH 5.5 Elcometer 4360/15 30μm 105oC 4min 1.3 3000HS 648 FINAT Testing 1, 8 z Marvlen Zetasizer 180° 2.1 Fig.1 (a) (b) 1.0g Conversion / % dz/ nm a100 80 60 40 20 instantaneous overall 0 0 60 120 180 240 300 360 Reaction time / min 400 b 350 300 250 200 150 100 0 60 theoretical m easured 120 180 240 300 360 Reaction tim e/ m in Fig.1 Conversion (a) and z-average particle size (b) versus reaction time of a PSA latex Fig.1 (a) using 1.0 g surfactant in the seed stage. 85% 98.6% 1% Fig.1 (b) P(BA-co-AA) [8] Tab.1 Tab.1 “” 1.0 2.5 5 7.5 20g Table.1 Particle size of seeds and final particles for the latexes prepared 1234 2.2 Fig.2 (g) Fig.3 (nm) (nm) 1.0 2.5 5.0 138 115 95 366 311 251 FINAT 1, 8 7.5 82 221 5 20 53 124 180° 649 Peel force/N/25mm Peel force/N/25mm 24 22 20 18 16 14 12 10 8 6 100 AT 50% a AF AF AF AF 150 200 250 300 350 Final particle size/nm 400 24 b22 20 18 AT 90% 16 14 12 10 8 6 100 150 AF AF 10% AT AF 200 250 300 Final particle size/nm 350 400 Fig.2 Variation of PSA peel force (180°, FINAT Test Method 1) with latex particle size after: (a) 20 min, (b) 24 hours. The mode of failure is indicated by: AF = adhesive failure; AT = adhesive transfer. Shear resistance/min 500 400 300 200 100 0 100 CF 150 CF CF CF CF 200 250 300 350 400 Fig.3 Variation of PSA shear resistance (FINAT Test Method 8) with latex particle size (CF = cohesive failure). Fig.2(a) 20min Fig.2(b) 24h Fig.2(b) 366 311 251 221 124nm 1.0 2.5 5 7.5 20g 0.4:0.8:1.3:1.8: 2.7 Fig.3 1 Peter A. Lovell, Mohamed S. El-Aasser, Emulsion polymerization and emulsion polymers, John Wiley Sons, New York, 1997 2 Istvan Benedek, Luc J. Heymans, Pressure-sensitive adhesives technology, Marcel Dekker, Inc., New York, 1997 650 3 John Garrett, Peter A. Lovell, Alison J. Shea and Roger D. Viney, Water-borne pressure-sensitive adhesives: effects of acrylic