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Counter-intuitive reduction of thermal contact resistance with porosity A case study of polymer electrolyte membrane fuel cells.pdf

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Counter-intuitive reduction of thermal contact resistance with porosity A case study of polymer electrolyte membrane fuel cells.pdf

i n t e r n a t i o n a l j o u r n a l o f h y d r o g e n e n e r g y 4 1 ( 2 0 1 6 ) 6 8 3 3 e6 8 4 1 Available online at ScienceDirect journal homepage: /locate/he Counter-intuitive reduction of thermal contact resistance with porosity: A case study of polymer electrolyte membrane fuel cells Hamidreza Sadeghifar a,b,c,d,*, Ned Djilali c, Majid Bahrami b a Department of Chemical and Biological Engineering, University of British Columbia, 2360 East Mall, Vancouver, BC V6T 1Z3, Canada b Laboratory for Alternative Energy Conversion (LAEC), School of Mechatronic Systems Engineering, Simon Fraser University, Surrey, BC V3T 0A3, Canada c Institute for Integrated Energy Systems and Energy Systems and Transport Phenomena Lab (ESTP), Department of Mechanical Engineering, University of Victoria, Victoria, BC V8W 3P6, Canada d Vancouver International CleanTech Research Institute, 4475 Wayburne Dr. Suite 310, Burnaby, BC V5G 4X4, Canada article info Article history: Received 23 July 2015 Received in revised form 8 March 2016 Accepted 9 March 2016 Available online 30 March 2016 Keywords: Contact resistance Porosity Micro porous layer (MPL) Gas diffusion layer (GDL) Fuel cells abstract The present study reveals that the conventional notion that thermal contact resistance increases with porosity does not necessary hold. It is proved through a mechanistic robust model that, under speci?c circumstances, the porosities of two contacting bodies attain a critical value beyond which the contact resistance counter-intuitively drops. The model focuses on micro porous layers (MPLs) coated on gas diffusion layers (GDLs) of polymer electrolyte membrane fuel cells (PEMFCs) and is validated with the MPL-GDL thermal contact resistance measured over a range of pressure. The counter-intuitive reduction of the contact resistance with porosity can ?nd important applications in energy conversion systems such as PEMFCs and batteries where contact resistance plays a major role in ohmic loss and he