Influence of the operating parameters and of the sample introduction system on time correlation of line intensities using an axially viewed CCD-based ICP-AES system.pdfVIP

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Influence of the operating parameters and of the sample introduction system on time correlation of line intensities using an axially viewed CCD-based ICP-AES system.pdf

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Influence of the operating parameters and of the sample introduction system on time correlation of line intensities using an axially viewed CCD-based ICP-AES system.pdf

Spectrochimica Acta Part B 65 (2010) 137–146 Contents lists available at ScienceDirect Spectrochimica Acta Part B j o u r n a l h o m e p a g e : w w w. e l s ev i e r. c o m / l o c a t e / s a b In?uence of the operating parameters and of the sample introduction system on time correlation of line intensities using an axially viewed CCD-based ICP-AES system Marco Grotti a,?, José Luis Todolí b, Jean Michel Mermet c a Dipartimento di Chimica e Chimica Industriale, Via Dodecaneso 31, 16146 Genova, Italy b Departamento de Química Analítica, Nutrición y Bromatología, Universidad de Alicante, 03080, Alicante, Spain c Spectroscopy Forever, 01390 Tramoyes, France article info Article history: Received 19 October 2009 Accepted 6 December 2009 Available online 13 December 2009 Keywords: Repeatability Internal standardization Time correlation Flicker-noise Shot-noise Sample introduction system Ultrasonic nebulization abstract The in?uence of the acquisition and operating parameters on time correlation between emission line intensities was investigated using axially viewed inductively coupled plasma-multichannel-based emission spectrometry and various sample introduction systems. It was found that to obtain ?icker-noise limited signals, necessary to compensate for time-correlated signal ?uctuations by internal standardization, the ?icker-noise magnitude of the sample introduction system, the integration time and the emission line intensity had to be considered. The highest correlation between lines was observed for ultrasonic nebulization with desolvatation, the noisiest system among those considered, for which the contribution of the uncorrelated shot-noise was negligible. In contrast, for sample introduction systems characterized by lower ?icker-noise levels, shot-noise led to high, non-correlated RSD values, making the internal standard method to be much less ef?cient. To minimize shot-noise, time correlation was improved by increasing the emission line intensities and the