Raman spectral characteristics of magmatic-contact metamorphic coals from Huainan Coalfield, China.pdfVIP
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Raman spectral characteristics of magmatic-contact metamorphic coals from Huainan Coalfield, China.pdf
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 171 (2017) 31–39
Contents lists available at ScienceDirect
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
journal homepage: /locate/saa
Raman spectral characteristics of magmatic-contact metamorphic coals from Huainan Coal?eld, China
Shancheng Chen a,c, Dun Wu a,b,c, Guijian Liu a,b,?, Ruoyu Sun a
a CAS Key Laboratory of Crust-Mantle Materials and Environment, School of Earth and Space Sciences, University of Science and Technology of China, Hefei, Anhui 230026, China b State Key Laboratory of Loess and Quaternary Geology, Institute of Earth Environment, The Chinese Academy of Sciences, Xian, Shaanxi 710075, China c Exploration Research Institute, Anhui Provincial Bureau of Coal Geology, Hefei, Anhui 230088, China
article info
Article history: Received 31 August 2015 Received in revised form 17 July 2016 Accepted 18 July 2016 Available online 19 July 2016
Keywords: Magmatic-contact metamorphosed coal Vitrinite re?ectance Raman spectroscopy Huainan Coal?eld
abstract
Normal burial metamorphism of coal superimposed by magmatic-contact metamorphism makes the characteristics of the Raman spectrum of coal changed. Nine coal samples were chosen at a coal transect perpendicular to the intrusive dike, at the No. 3 coal seam, Zhuji Coal Mine, Huainan Coal?eld, China, with different distances from dike-coal boundary (DCB). Geochemical (proximate and ultimate) analysis and mean random vitrinite re?ectance (R0, %) indicate that there is a signi?cant relationship between the values of volatile matter and R0 in metamorphosed coals. Raman spectra show that the graphite band (G band) becomes the major band but the disordered band (D band) disappears progressively, with the increase of metamorphic temperature in coals, showing that the structural organization in high-rank contact-metamorphosed coals is close to that of well-crystallized graphite. Evident relationships are observed between the cal
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