Soft-contact conductive carbon enabling depolarization of LiFePO4 cathodes to enhance both capacity and rate performances of lithium ion batteries.pdfVIP

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Soft-contact conductive carbon enabling depolarization of LiFePO4 cathodes to enhance both capacity and rate performances of lithium ion batteries.pdf

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Soft-contact conductive carbon enabling depolarization of LiFePO4 cathodes to enhance both capacity and rate performances of lithium ion batteries.pdf

Journal of Power Sources 331 (2016) 232e239 Contents lists available at ScienceDirect Journal of Power Sources journal homepage: /locate/jpowsour Soft-contact conductive carbon enabling depolarization of LiFePO4 cathodes to enhance both capacity and rate performances of lithium ion batteries Wenju Ren 1, Kai Wang 1, Jinlong Yang**, Rui Tan, Jiangtao Hu, Hua Guo, Yandong Duan, Jiaxin Zheng, Yuan Lin, Feng Pan* School of Advanced Materials, Peking University, Shenzhen Graduate School, Shenzhen, 518055, Peoples Republic of China highlights The mechanism of conductive nanocarbons enhance LIBss performance is proposed. Three types of nanocarbons and related performances in LFP electrodes are studied. SCC can generate much larger contact area than that of HCC. LFP nano-crystals wrapped in SCC perform signi?cantly enhanced. Combined experiments with multiphysics simulation, the mechanism is elaborated. article info Article history: Received 8 July 2016 Received in revised form 3 September 2016 Accepted 9 September 2016 Available online 17 September 2016 Keywords: Soft-contact conductive carbon LiFePO4 Depolarization Multiphysics simulation Li-ions batteries abstract Conductive nanocarbons generally are used as the electronic conductive additives to contact with active materials to generate conductive network for electrodes of commercial Li-ion batteries (LIBs). A typical of LiFePO4 (LFP), which has been widely used as cathode material for LIBs with low electronic conductivity, needs higher quantity of conductive nanocarbons to enhance the performance for cathode electrodes. In this work, we systematically studied three types of conductive nanocarbons and related performances in the LFP electrodes, and classify them as hard/soft-contact conductive carbon (named as H/SCC), respectively, according to their crystallite size, surface graphite-defect, speci?c surface area and porous structure, in which SCC can generate much larger contact area with active nano-particle