Some remarks on the solid surface tension determination from contact angle measurements.pdfVIP

Some remarks on the solid surface tension determination from contact angle measurements.pdf

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Some remarks on the solid surface tension determination from contact angle measurements.pdf

Applied Surface Science 405 (2017) 88–101 Contents lists available at ScienceDirect Applied Surface Science journal homepage: /locate/apsusc Full Length Article Some remarks on the solid surface tension determination from contact angle measurements Anna Zdziennicka, Katarzyna Szymczyk, Joanna Krawczyk, Bronis?aw Jan′ czuk ? Department of Interfacial Phenomena, Faculty of Chemistry, Maria Curie-Sk?odowska University, Maria Curie-Sk?odowska Sq. 3, 20-031, Lublin, Poland article info Article history: Received 29 November 2016 Received in revised form 5 January 2017 Accepted 8 January 2017 Available online 7 February 2017 Keywords: Surface tension Contact angle Polymers Quartz Silica abstract The measurements of water, formamide and diiodomethane contact angle (?) on polytetra?uoroethylene (PTFE), polyethylene (PE), polymethyl methacrylate (PMMA), nylon 6, quartz and silica were performed. Based on the ? values of these liquids obtained on PTFE, the Lifshitz-van der Waals and acid-base and/or dispersion and polar components of their surface tension (ST) were determined. In turn, the ? values for water, formamide and diiodomethane on PMMA were applied to calculate the electron-acceptor and electron-donor parameters of the Lewis acid-base component of the formamide ST. For this calculation the same values of the electron-acceptor and electron-donor parameters for water ST were used. Taking into account the values of components and parameters of water, formamide and diiodomethane ST obtained by us, van Oss et al. and from the water(formamide)-n-alkane and water-diiodomethane interface tension, the components and parameters of studied solids ST were calculated. To this end different approaches to the interface tension were considered. The obtained values were compared with those in the literature. It was concluded that for determination of solid ST components and parameters, those of water, formamide and diiodomethane ST obtained from the ? measurements on the model solids

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