TEOSsilane coupling agent composed double layers structure A novel super-hydrophilic coating with controllable water contact angle value.pdfVIP

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TEOSsilane coupling agent composed double layers structure A novel super-hydrophilic coating with controllable water contact angle value.pdf

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TEOSsilane coupling agent composed double layers structure A novel super-hydrophilic coating with controllable water contact angle value.pdf

Applied Energy 185 (2017) 2209–2216 Contents lists available at ScienceDirect Applied Energy journal homepage: /locate/apenergy TEOS/silane coupling agent composed double layers structure: A novel super-hydrophilic coating with controllable water contact angle value q Hu Yan a, Wang Yuanhao b,?, Yang Hongxing a a Renewable Energy Research Group (RERG), Department of Building Services Engineering, The Hong Kong Polytechnic University, Hong Kong b Faculty of Science and Technology, Technological and Higher Education Institute of Hong Kong, New Territories, Hong Kong highlights We made a tranparent super-hydrophilic glass coating via a silane coupling agent. We used TEOS to enhance the adhesion force of the coating. We ?tted the exponential formulas describing the relation between contact angle values and the silane coupling agent’s concentrations. article info Article history: Received 2 June 2015 Received in revised form 11 September 2015 Accepted 29 September 2015 Available online 2 November 2015 Keywords: Silane coupling agent Self-cleaning Super-hydrophilic TEOS Contact angle abstract The soiling of the photovoltaic (PV) modules’ front surfaces decreases the power generation ef?ciency a lot. In this paper, a novel self-cleaning (super-hydrophilic) glass coating material with double layers’ structure is prepared and the synthesis process is simple and low-price. This super-hydrophilic coating barely decreases the transparency of the glass above solar cells in the PV modules. It only reduces about 2.9% of transparency compared with original glass. Brie?y, TEOS (Tetraethylorthosilicate) is skillfully utilized as hydrophobic interlayer, connected to the substrate surface and super-hydrophilic layer, whose effective component is a particular silane-coupling agent named as 2-[acetoxy (polyethyleneoxy) propyl] triethoxysilane (abbreviated as SIA). The interlayer has three advantages: ?rstly, after the TEOS hydrophobic layer is coated, SIA’s hydrophobic siloxane ter