反相悬浮聚合法制备三聚氰胺甲醛树脂包覆红磷（英文）.docVIP

反相悬浮聚合法制备三聚氰胺甲醛树脂包覆红磷（英文） 　　摘要通过反相悬浮聚合法制备了三聚氰胺甲醛（MF）树脂微胶囊包覆红磷，采用红外光谱（FIIR）、扫描电子显微镜（SEM）、X射线光电子能谱（XPS）对其结构进行了表征，并对微胶囊红磷与聚丙烯（PP）及尼龙6（PA6）形成的复合物的极限氧指数进行了分析，评价了微胶囊红磷的热性能，测试了其在PP及PA6复合物中的阻燃效率.实验结果表明，三聚氰胺甲醛树脂被成功包覆在红磷颗粒的表面.当微胶囊红磷的添加质量分数为15%时，PA6/MRP的极限氧指数LOI大于28.2%，而PP/MRP的极限氧指数LOI大于22.4%. 　　关键词反相悬浮聚合； 三聚氰胺甲醛树脂；微胶囊包覆；红磷 　　Red phosphorus （RP） has become one of the efficient， ecological and the most harmless additives for fire retardant polymers [1]. As a fire retardant additive， the phosphorus is required to be in fine particle size to have less negative effect on the mechanical properties of fire retardant polymer composites. However， phosphorus with very fine particle is highly flammable especially at elevated temperature in the presence of moisture and atmospheric oxygen. In addition， surfacemodification is also required to improve the interfacial interactions between polymer matrix and phosphorus. The most widely used technique is inorganic or polymeric microencapsulation[29]. In polymeric microencapsulation， the thermosetting resins including epoxy resin， melamine formaldehyde， urea formaldehyde and phenolic formaldehyde resins were preferably used[1012]. Typically， phosphorus powders were suspended in a polymeric aqueous solution at higher temperature； once the temperature was cooled down， suspended phosphorus particles were coated with the precipitated polymers. The encapsulated phosphorus was obtained after filtration. In this process， a large quantity of water with dissolved polymers needs to be treated[13]. In this study， inverse suspension polymerization method was applied in the preparation of melamine formaldehyde resin coated red phosphorus. Higher coating efficiency of polymers and lower waste water were expected in this method. 　　1Experimental 　　1.1Materials 　　Red phosphorus powder with a particle size of about 600 mesh was provided by Luxi Songgong HiTech Co.， Ltd （China）； Soybean oil was provided by Xinsha cereals and oils Co.， Ltd （China）； Melam