基于渗透理论的液液微混合体系传质模型.pdfVIP

1.6×10-3m2/s TQ051.83 TQ051.893 A MASS TRANSFER MODEL BASED ON PENETRATION THEORY FOR LIQUID- LIQUID MICROMIXING SYSTEMS XU Jianhong LUO Guangsheng SUN Yong CHEN Guiguang and WANG Jiading (The State Key Laboratory of Chemical Engineering, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China) Abstract The mass transfer performance in micromixing process is much higher than that in a conventional extraction process because of micro-scale droplet size. But the mass transfer mechanism in the micromixing process has not been reported yet. In order to investigate the mass transfer performance in the micromixing process, some traditional models have been applied to predict the mass transfer coefficients. The results showed that the mass transfer coefficients in the micromixing process reached as much as 1.6×10-3m2/s, which is about more than 100 times higher than that in a traditional extraction process. The traditional models could not predict the mass transfer coefficients accurately. It indicates that the mass transfer performances in the micromixing process are quite :. : , , 25 , (No.20176022) Corresponding author: LUO Guangsheng . E-mail: gsluo@tsinghua.edu.cn different from the traditional extraction process. A new mathematical model based on pernetration theory has been developed, and the mass transfer coefficients were calculated with the model. The calculated values using the model were in good agreement with the experimental data. Keywords extraction, mass transfer model, mass transfer coefficient, liquid-liquid micromixing —— [1,2] [3,4] [5] —— [8,9] [6,7] [10,11] 5μm // // 30%TBP- / / - - E = c ci ? c0 ? c0 N = kdA(cdi ? cd ) kdA(cdi ? cd )dt = Vddcd kd = ? d 6t ln(1? E) -- 1 Table 1 Mass transfer models [12-13] Mass transfer in drop Stagnant Newman’s model: Full model Laminar circulating ∑kd = ? d 6t ln[ 6 π2 ∞ n =1 1 n2 exp( ? 4n 2 π 2 Dd d2 t )] Kronig and Brink’s model: ∑kd = ? d 6t ln[ 3 8 ∞ n=1 B2n exp(? 64λ n D d d2 t